Effect of Solution Temperature on Microstructure and Mechanical Properties of Cu-3.4Ti Alloys

YANG Yunxi, QIANG Fengming, WANG Wen, ZHANG Yuye, XUE Zetian, MA Qianzhi, LI Yunbo, LIU Yilin, SUN Yongliang, WANG Kuaishe

Journal of Netshape Forming Engineering ›› 2026, Vol. 18 ›› Issue (2) : 259-265.

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Journal of Netshape Forming Engineering ›› 2026, Vol. 18 ›› Issue (2) : 259-265. DOI: 10.3969/j.issn.1674-6457.2026.02.024
Copper Alloy Forming

Effect of Solution Temperature on Microstructure and Mechanical Properties of Cu-3.4Ti Alloys

  • YANG Yunxi, QIANG Fengming*, WANG Wen, ZHANG Yuye, XUE Zetian, MA Qianzhi, LI Yunbo, LIU Yilin, SUN Yongliang, WANG Kuaishe*
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Abstract

The work aims to investigate the re-dissolution behavior of the primary phase in Cu-3.4Ti alloys and its effect on the synergistic regulation of microstructural evolution and mechanical properties under different solution treatment temperature, so as to provide a theoretical basis for the optimization of subsequent aging and forming processes for Cu-Ti alloys. Based on the Cu-Ti phase diagram, solution treatments were performed at 800, 850, 900, and 950 ℃. X-ray diffraction (XRD) was used to analyze the phase composition. Optical microscopy (OM) was employed for microstructural observation to examine the grain morphology. Scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS) and electron backscatter diffraction (EBSD) was utilized for compositional and microstructural analysis. Tensile tests were conducted at room temperature to measure the tensile strength and elongation of the alloys. The results indicated that at solution treatment temperature of 800-950 ℃, the Cu3Ti primary phase in the as-forged alloy was largely re-dissolved, significantly increasing the matrix's supersaturation. As the temperature increased, the alloy grain size grew progressively, with abnormal grain growth and grain boundary overburning observed at 950 ℃, leading to a decrease in structural stability. Mechanical testing revealed that the tensile strength increased initially and then decreased with the temperature rise, while the elongation continuously decreased. The solution treatment temperature has a significant impact on the microstructure, mechanical properties, and formability of the forged alloy. After solution treatment at 850 ℃ for 1 h, the Cu-3.4Ti alloys exhibit the best overall performance, with a tensile strength of 527.3 MPa and an elongation of 51.1%, along with improved formability.

Key words

Cu-Ti alloys / solution treatment / primary phase / microstructure evolution / mechanical properties

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YANG Yunxi, QIANG Fengming, WANG Wen, ZHANG Yuye, XUE Zetian, MA Qianzhi, LI Yunbo, LIU Yilin, SUN Yongliang, WANG Kuaishe. Effect of Solution Temperature on Microstructure and Mechanical Properties of Cu-3.4Ti Alloys[J]. Journal of Netshape Forming Engineering. 2026, 18(2): 259-265 https://doi.org/10.3969/j.issn.1674-6457.2026.02.024

References

[1] 苑和锋, 徐玲. 弹性铜合金研究现状及发展趋势[J]. 湖南有色金属, 2014, 30(3): 46-49.
[2] YUAN H F, XU L.Research Status and Development Trend of the Elastic Copper Alloy[J]. Hunan Nonferrous Metals, 2014, 30(3): 46-49.
[3] 代雪琴, 贾淑果, 范俊玲, 等. 高强高导铜合金的强化机理与研究热点[J]. 材料热处理学报, 2021, 42(10): 18-26.
[4] DAI X Q, JIA S G, FAN J L, et al.Strengthening Mechanism and Research Focus of High Strength and High Conductivity Copper Alloy[J]. Transactions of Materials and Heat Treatment, 2021, 42(10): 18-26.
[5] 黄富, 余方新, 冯桄波, 等. 高强铜钛合金的发展与应用[J]. 特种铸造及有色合金, 2020, 40(5): 502-506.
[6] HUANG F, YU F X, FENG G B, et al.Development and Application of High Strength and High Elasticity Copper-Titanium Alloys[J]. Special Casting & Nonferrous Alloys, 2020, 40(5): 502-506.
[7] 卫欢, 卫英慧, 侯利锋. 时效硬化铜钛合金的相变和应用[J]. 功能材料, 2015, 46(10): 10001-10006.
[8] WEI H, WEI Y H, HOU L F.The Phase Transition and Applications of Age Hardening Copper-Titanium Alloys[J]. Journal of Functional Materials, 2015, 46(10): 10001-10006.
[9] IKEDA J, SEMBOSHI S, IWASE A, et al.Precipitation Behavior and Properties of Cu-Ti Alloys with Added Nitrogen[J]. Materials Transactions, 2015, 56(3): 297-302.
[10] LIAO Y M, GUO C J, ZHOU C Y, et al.Stabilization of the Metastable βʹ Phase by Forming Cu4(Ti, Sc) Crystal Structure in Cu-Ti Alloys[J]. Journal of Materials Research and Technology, 2024, 31: 3526-3535.
[11] SUK H G, HONG H S.Effects of Alloying Element and Heat Treatment on Properties of Cu-Ti Alloys[J]. Journal of the Korean Institute of Surface Engineering, 2009, 42(5): 246-249.
[12] HAN Z Y, ZHOU M, JING K, et al.Microstructure and Hot Deformation Behavior of Cu-Ti-Zr(-Mg) Alloys[J]. Journal of Materials Research and Technology, 2024, 33: 5490-5503.
[13] DAI X Q, JIA S G, ZHOU Y J, et al.Microstructural Evolution and Properties of the Cu-Cr-Ti Alloys after Cold Deformation and Subsequent Aging Treatment[J]. Progress in Natural Science: Materials International, 2024, 34(6): 1258-1266.
[14] 刘位江. Cu-3.2Ti-0.2Fe-xV合金异质结构调控及强塑性提升机理研究[D]. 赣州: 江西理工大学, 2022: 7-8.
[15] LIU W J.Study on Heterostructure Regulation and Mechanism of Strength-Ductility Synergy Improvement in Cu-3.2Ti-0.2Fe-xV Alloys[D]. Ganzhou: Jiangxi University of Science and Technology, 2022: 7-8.
[16] WANG X, XIAO Z, CHEN Y, et al.Suppression of Discontinuous Precipitation by Fe Addition in Cu-Ti Alloys[J]. Rare Metals, 2025, 44(3): 1982-1997.
[17] WANG X, DING Y J, JIANG X F, et al.Effects of Fe Content on Properties and Microstructure of Cu-Ti Alloys during Aging[J]. Journal of Materials Research and Technology, 2023, 27: 5518-5532.
[18] XU B F, WANG Q J, WANG W, et al.Precipitation Behavior and Performance Evolution of Cold-Rolled Cu-Ti-Fe Alloy during Heat Treatment[J]. Materials Characterization, 2024, 217: 114388.
[19] YANG K, GUO M X, WANG H, et al.Synergistically Improved Strength and Electrical Conductivity of Cu-3.3wt%Ti Alloy via Coupling Control of Dislocation and Multi-Scale Precipitates[J]. Materials Science and Engineering: A, 2024, 915: 147259.
[20] XIN G A, ZHOU M, JING K, et al.Heat Treatment Effects on Microstructure and Properties of Cu-Ti-Fe Alloys[J]. Materials Science and Engineering: A, 2024, 892: 146068.
[21] ZHANG F, SHEN J, LIN Y C, et al.Microstructure and Property of 2099 Alloy with Different Solid Solution Processes[J]. Chinese Journal of Rare Metals, 2017, 41(4).
[22] LIU C, SONG Z Y, FAN Y G, et al.Growth Kinetics of Intermetallic Compounds in Cu-Ti Diffusion Couples[J]. Intermetallics, 2024, 168: 108261.
[23] LIU C, FAN Y G, ROGALIN V E, et al.Growth Behaviors of Primary CuTi Phase in a Hypoeutectic Cu-Ti Alloy[J]. Metallurgical and Materials Transactions B, 2025, 56(2): 1047-1051.
[24] EZE A A, JAMIRU T, SADIKU E R, et al.Effect of Titanium Addition on the Microstructure, Electrical Conductivity and Mechanical Properties of Copper by Using SPS for the Preparation of Cu-Ti Alloys[J]. Journal of Alloys and Compounds, 2018, 736: 163-171.
[25] 李兵, 陈文轩, 张红霞, 等. 固溶温度和保压淬火时间对7075铝合金板材组织和性能的影响[J]. 精密成形工程, 2024, 16(11): 144-150.
[26] LI B, CHEN W X, ZHANG H X, et al.Effect of Solid Solution Temperature and Holding and Quenching Time on the Microstructure and Properties of 7075 Aluminum Alloy Plates[J]. Journal of Netshape Forming Engineering, 2024, 16(11): 144-150.
[27] 梁海成, 惠文芃, 陈帅峰, 等. 固溶处理及工艺路径对Cu-Ni-Si-Co合金板材性能的影响[J]. 精密成形工程, 2024, 16(7): 144-152.
[28] LIANG H C, HUI W P, CHEN S F, et al.Effect of Solid Treatment and Process Route on Properties of Cu-Ni-Si- Co Alloy Sheet[J]. Journal of Netshape Forming Engineering, 2024, 16(7): 144-152.
[29] 王丽霞, 李念涛. 固溶处理和时效处理对A356铝合金性能的影响及较优处理温度确定[J]. 精密成形工程, 2024, 16(8): 138-147.
[30] WANG L X, LI N T.Effects of Solution Treatment and Aging Treatment on the Properties of A356 Aluminum Alloy and Determination of Optimal Treatment Temperature[J]. Journal of Netshape Forming Engineering, 2024, 16(8): 138-147.
[31] SZKLINIARZ A.Formation of Microstructure and Properties of Cu-3Ti Alloy in Thermal and Thermomechanical Processes[J]. Archives of Metallurgy and Materials, 2017, 62(1): 223-230.
[32] 张楠, 李振华, 姜训勇, 等. Ti含量对Cu-Ti合金时效过程的影响[J]. 材料热处理学报, 2016, 37(3): 36-40.
[33] ZHANG N, LI Z H, JIANG X Y, et al.Influence of Ti Content on Aging Process of Cu-Ti Alloys[J]. Transactions of Materials and Heat Treatment, 2016, 37(3): 36-40.
[34] SOFFA W A, LAUGHLIN D E.High-Strength Age Hardening Copper-Titanium Alloys: Redivivus[J]. Progress in Materials Science, 2004, 49(3/4): 347-366.

Funding

National Key R&D Program of China (2023YFB3710003)
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