变形温度对热挤压态纯铜织构演化的影响

李龙豪, 刘皓岚, 胡浩, 李习耀, 王江伟, 宋克兴

精密成形工程 ›› 2026, Vol. 18 ›› Issue (9) : 159-167.

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精密成形工程 ›› 2026, Vol. 18 ›› Issue (9) : 159-167. DOI: 10.3969/j.issn.1674-6457.2026.09.016
铜合金成形

变形温度对热挤压态纯铜织构演化的影响

  • 李龙豪1,2, 刘皓岚1,*, 胡浩2, 李习耀1, 王江伟1, 宋克兴1
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Effect of Deformation Temperature on Texture Evolution in Hot-extruded Copper

  • LI Longhao1,2, LIU Haolan1,*, HU Hao2, LI Xiyao1, WANG Jiangwei1, SONG Kexing1
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摘要

目的 系统分析变形过程中温度对热挤压态高纯铜织构演化及宏观力学性能的影响机制,为理解挤压态纯铜在力-热耦合环境下的织构演化及性能调控提供了新见解。方法 基于原位背散射电子衍射(In-situ EBSD)技术,对热挤压态纯铜分别进行室温和高温原位拉伸实验,以关联微观组织演变与宏观力学行为。结果 温度显著影响织构演化路径,尤其在6%~15%塑性应变区间内差异明显。室温变形时,晶粒倾向于向软取向转动,致使<100>(//LD)软织构含量显著升高,从而表现出相对较低的屈服强度与抗拉强度。相比之下,在高温条件下,晶粒向<100>软织构的转变受到抑制,<111>和<112>(//LD)硬织构比例显著上升,引入额外加工硬化效应,使极限抗拉强度提升至79.1 MPa,同时塑性进一步改善。结论 高温改变了潜在的位错动力学行为,进而影响了晶粒旋转路径,促使<111>和<112>硬织构形成,从而提升了材料强度;此外,高温下动态回复过程与小角度晶界、几何必需位错密度降低的协同作用,有效缓解了局部应力集中,提升了材料的塑性变形能力。

Abstract

The work aims to systematically analyze the mechanisms by which temperature influences texture evolution and macroscopic mechanical properties of hot-extruded high-purity copper during deformation, so as to provide new insights for understanding texture evolution and property optimization under thermo-mechanical coupling environments. In-situ tensile experiments were conducted on hot-extruded pure copper at both room temperature and elevated temperature using in-situ electron backscatter diffraction (EBSD) to correlate microstructural evolution with the macroscopic mechanical behavior. Temperature significantly influenced the texture evolution pathway, with a distinct divergence observed particularly within the 6%-15% plastic strain interval. During room temperature deformation, grains tend to rotated towards soft orientations, resulting in a significant increase in the fraction of <100> soft texture (//LD) and consequently exhibiting relatively lower yield and tensile strengths. In contrast, elevated temperature conditions suppressed the transition towards the <100> soft texture and instead promoted a significant increase in the proportion of <111> and <112> hard textures. This accumulation contributed to an extra work hardening, enhancing the ultimate tensile strength by 79.1 MPa while concurrently increasing ductility. It is concluded that high temperature alters the underlying dislocation dynamics, thereby modifying grain rotation paths to favor the formation of <111> and <112> hard textures, which enhances material strength. Furthermore, the synergistic effect of dynamic recovery and the reduction in the densities of low-angle grain boundaries (LAGBs) and geometrically necessary dislocations (GNDs) effectively weaken the local stress concentrations, thereby enhancing the plasticity.

关键词

高纯铜 / 热挤压态 / 织构演化 / 力学性能 / 原位研究

Key words

high-purity copper / hot-extruded / texture evolution / mechanical properties / in-situ research

引用本文

导出引用
李龙豪, 刘皓岚, 胡浩, 李习耀, 王江伟, 宋克兴. 变形温度对热挤压态纯铜织构演化的影响[J]. 精密成形工程. 2026, 18(9): 159-167 https://doi.org/10.3969/j.issn.1674-6457.2026.09.016
LI Longhao, LIU Haolan, HU Hao, LI Xiyao, WANG Jiangwei, SONG Kexing. Effect of Deformation Temperature on Texture Evolution in Hot-extruded Copper[J]. Journal of Netshape Forming Engineering. 2026, 18(9): 159-167 https://doi.org/10.3969/j.issn.1674-6457.2026.09.016
中图分类号: TG146.11   

参考文献

[1] 张彦敏, 王永健, 陈赛, 等. Cu-Al2O3(0.68%)弥散强化铜合金塑性变形特性[J]. 精密成形工程, 2017, 9(5): 128-133.
ZHANG Y M, WANG Y J, CHEN S, et al.Plastic Deformation Characteristics of Cu-Al2O3(0.68%) Dispersion Strengthened Copper Alloy[J]. Journal of Netshape Forming Engineering, 2017, 9(5): 128-133.
[2] KHANDELWAL P, MANNA I.Intelligent Design of High Strength and High Conductivity Copper Alloys Using Machine Learning Assisted by Genetic Algorithm[J]. Computers, Materials & Continua, 2024, 79(1): 1727-1755.
[3] YAN H, HU H L, LI L, et al.Research Progress of Cu-Ni-Si Series Alloys for Lead Frames[J]. Coatings, 2025, 15(1): 91.
[4] ZHANG W J, HUANG L, MI X J, et al.Researches for Higher Electrical Conductivity Copper-Based Materials[J]. cMat, 2024, 1(1): e13.
[5] 李习耀, 刘皓岚, 翟晓玉, 等. 单晶铌低温剪切带形成与演化的透射电镜研究[J]. 电子显微学报, 2024, 43(5): 557-563.
LI X Y, LIU H L, ZHAI X Y, et al.Formation and Evolution of Shear Band in Single Crystal Niobium Deformed at Low Temperature Based on TEM Study[J]. Journal of Chinese Electron Microscopy Society, 2024, 43(5): 557-563.
[6] 王江伟, 陈映彬, 祝祺, 等. 金属材料的晶界塑性变形机制[J]. 金属学报, 2022, 58(6): 726-745.
WANG J W, CHEN Y B, ZHU Q, et al.Grain Boundary Dominated Plasticity in Metallic Materials[J]. Acta Metallurgica Sinica, 2022, 58(6): 726-745.
[7] 邹景锋, 郭星晨, 孙栋, 等. 镁合金棒材径向锻造-挤压成型过程组织及性能研究[J]. 精密成形工程, 2025, 17(11): 190-200.
ZOU J F, GUO X C, SUN D, et al.Microstructure and Properties of Magnesium Alloy Bar during Radial Forging-Extrusion Forming Process[J]. Journal of Netshape Forming Engineering, 2025, 17(11): 190-200.
[8] 李习耀, 王江伟. 体心立方金属的变形孪生行为[J]. 机械工程材料, 2023, 47(5): 102-108.
LI X Y, WANG J W.Deformation Twinning Behaviors of Body-Centered Cubic Metals[J]. Materials for Mechanical Engineering, 2023, 47(5): 102-108.
[9] 祁志旭, 岳鹏飞, 李习耀, 等. 铜基金属纳米多层膜界面介导的损伤及断裂行为原位研究进展[J]. 精密成形工程, 2024, 16(9): 13-21.
QI Z X, YUE P F, LI X Y, et al.In-Situ Research of Interface-Mediated Damage and Fracture Behavior of Cu Based Nanostructured Metallic Multilayers[J]. Journal of Netshape Forming Engineering, 2024, 16(9): 13-21.
[10] 孙捷, 曲京儒, 阎玉芹, 等. 稀土元素对轧制Mg-Zn- Zr合金板材微观组织和力学性能的影响[J]. 精密成形工程, 2023, 15(7): 129-135.
SUN J, QU J R, YAN Y Q, et al.Effect of Rare Earth(RE) on Microstructure and Mechanical Property of Rolled Mg-Zn-Zr Alloy Plate[J]. Journal of Netshape Forming Engineering, 2023, 15(7): 129-135.
[11] BRONKHORST C A, KALIDINDI S R, ANAND L.Polycrystalline Plasticity and the Evolution of Crystallographic Texture in FCC Metals[J]. Philosophical Transactions of the Royal Society of London Series A: Physical and Engineering Sciences, 1992, 341(1662): 443-477.
[12] SAVOIE J, ZHOU Y, JONAS J J, et al.Textures Induced by Tension and Deep Drawing in Aluminum Sheets[J]. Acta Materialia, 1996, 44(2): 587-605.
[13] PÉREZ-PRADO M T, GONZÁLEZ-DONCEL G, RUANO O A, et al. Texture Analysis of the Transition from Slip to Grain Boundary Sliding in a Discontinuously Recrystallized Superplastic Aluminum Alloy[J]. Acta Materialia, 2001, 49(12): 2259-2268.
[14] DILLAMORE I L, KATOH H.The Mechanisms of Recrystallization in Cubic Metals with Particular Reference to Their Orientation-Dependence[J]. Metal Science, 1974, 8(1): 73-83.
[15] BASSON F, DRIVER J H.Deformation Banding Mechanisms during Plane Strain Compression of Cube- Oriented FCC Crystals[J]. Acta Materialia, 2000, 48(9): 2101-2115.
[16] QI L, TIAN W B, LV M Y, et al.Texture Evolution and Strengthening Mechanism of Single-Crystal Cu-2wt%Ag Alloy during Continuous Drawing[J]. Materials Science and Engineering: A, 2025, 947: 149202.
[17] FAN X Y, HOU J P, WANG S, et al.Achieving Extraordinary Strength and Conductivity in Copper Wire by Constructing Highly Consistent Hard Texture and Ultra-High Aspect Ratio[J]. Journal of Materials Science & Technology, 2025, 220: 14-22.
[18] LI X, ZHOU Y J, LIU Y H, et al.Texture Evolution and Its Influence Mechanism on Properties of Single Crystal Copper and Polycrystalline Copper during Cumulative Deformation[J]. Journal of Materials Research and Technology, 2023, 24: 6808-6819.
[19] GHOLAMI M, ALTENBERGER I, VESELY J, et al.Effects of Severe Plastic Deformation on Transformation Kinetics of Precipitates in CuNi3Si1Mg[J]. Materials Science and Engineering: A, 2016, 676: 156-164.
[20] VAUGHAN M W, LIM H, PHAM B, et al.The Mechanistic Origins of Heterogeneous Void Growth during Ductile Failure[J]. Acta Materialia, 2024, 274: 119977.
[21] WANG Y J, HUANG M S, LI Z H.Void Nucleation in Heterogeneous Materials Induced by Particle-Matrix Debonding in Polycrystalline Matrix[J]. European Journal of Mechanics-A, 2026, 116: 105899.
[22] GARRISON W M, MOODY N R.Ductile Fracture[J]. Journal of Physics and Chemistry of Solids, 1987, 48(11): 1035-1074.
[23] LIN Y C, CHEN X M.A Critical Review of Experimental Results and Constitutive Descriptions for Metals and Alloys in Hot Working[J]. Materials & Design, 2011, 32(4): 1733-1759.
[24] CHEN T T, WEN M, CUI H, et al.Hot Deformation Behavior and Processing Maps of Pure Copper during Isothermal Compression[J]. Materials, 2023, 16(11): 3939.
[25] LIU J Q, YIN Q, HE B W, et al.Molecular Dynamics Approach for Controlling Triaxial Stress States and Its Application to Void Evolution in Nano-Grained Polycrystals[J]. Journal of Applied Physics, 2025, 137(16): 165101.
[26] TAYLOR G I.Plastic Strain in Metals[J]. Journal of the Institute of Metals, 1938, 62: 307-324.
[27] CHE B, LU L W, ZHANG J L, et al.Effects of Cryogenic Treatment on Microstructure and Mechanical Properties of AZ31 Magnesium Alloy Rolled at Different Paths[J]. Materials Science and Engineering: A, 2022, 832: 142475.
[28] LOPES A B, BARLAT F, GRACIO J J, et al.Effect of Texture and Microstructure on Strain Hardening Anisotropy for Aluminum Deformed in Uniaxial Tension and Simple Shear[J]. International Journal of Plasticity, 2003, 19(1): 1-22.
[29] BAI Y B, ZHANG R, CUI C Y, et al.In-Situ Observation of Ni-Co Based Wrought Superalloy High-Temperature Deformation: Lattice Rotation and Grain Boundary Response[J]. Materials Research Letters, 2024, 12(11): 869-876.
[30] ZHANG Z W, LI Z, LIU Y, et al.Path Dependency of Plastic Deformation in Crystals: Work Hardening, Crystallographic Rotation and Dislocation Structure Evolution[J]. Crystals, 2022, 12(7): 999.
[31] ZHANG K, HOLMEDAL B, MÁNIK T, et al. Assessment of Advanced Taylor Models, the Taylor Factor and Yield-Surface Exponent for FCC Metals[J]. International Journal of Plasticity, 2019, 114: 144-160.
[32] ROBINSON J M, SHAW M P.Microstructural and Mechanical Influences on Dynamic Strain Aging Phenomena[J]. International Materials Reviews, 1994, 39(3): 113-122.
[33] YAN Z R, SRIKAKULAPU K, GAO Y, et al.γ’-Size Effect on the Deformation Microstructure and Texture in a Ni-Based Superalloy Using In-Situ Neutron Diffraction[J]. Scripta Materialia, 2023, 236: 115665.
[34] ALABORT E, BARBA D, SULZER S, et al.Grain Boundary Properties of a Nickel-Based Superalloy: Characterisation and Modelling[J]. Acta Materialia, 2018, 151: 377-394.
[35] OJIMA M, ADACHI Y, SUZUKI S, et al.Stress Partitioning Behavior in an Fcc Alloy Evaluated by the in Situ/Ex Situ EBSD-Wilkinson Method[J]. Acta Materialia, 2011, 59(10): 4177-4185.
[36] ZHAO W, XIANG H L, ZHAN X M, et al.Microstructure Evolution in Laser Powder Bed Fusion Melted 2205 Duplex Stainless Steel Using In-Situ EBSD during Uniaxial Tensile Testing[J]. Journal of Materials Research and Technology, 2024, 33: 2113-2124.
[37] HUMPHREYS F J, HATHERLY M.Recrystallization and Related Annealing Phenomena[M]. 2nd ed. Elsevier, 2012.
[38] KOCKS U F, MECKING H.Physics and Phenomenology of Strain Hardening: The FCC Case[J]. Progress in Materials Science, 2003, 48(3): 171-273.
[39] DANG K, SURESH S, MISHRA A, et al.Dislocation-Grain Boundary Interaction Dataset for FCC Cu[J]. Scientific Data, 2025, 12: 955.

基金

国家自然科学基金(52401009); 河南省科协青年人才托举工程(2025HYTP044); 河南省科学院基本科研业务费项目(240617059)

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