增材制造铜基材料的工艺、组织与性能研究进展

牛敬涵, 邓海亮, 王沛, 郭利萍, 梁士杰, 蔡嘉伟, 付志强, 徐继福

精密成形工程 ›› 2026, Vol. 18 ›› Issue (8) : 14-33.

PDF(53548 KB)
PDF(53548 KB)
精密成形工程 ›› 2026, Vol. 18 ›› Issue (8) : 14-33. DOI: 10.3969/j.issn.1674-6457.2026.08.002
高端能源、航空航天装备部件精密成形关键技术

增材制造铜基材料的工艺、组织与性能研究进展

  • 牛敬涵1, 邓海亮1,*, 王沛2, 郭利萍2, 梁士杰3, 蔡嘉伟4, 付志强4, 徐继福5
作者信息 +

Research Progress on the Process, Microstructure, and Properties of Additively Manufactured Copper-based Materials

  • NIU Jinghan1, DENG Hailiang1,*, WANG Pei2, GUO Liping2, LIANG Shijie3, CAI Jiawei4, FU Zhiqiang4, XU Jifu5
Author information +
文章历史 +

摘要

铜基材料因具有优异的导电性、导热性、延展性、耐腐蚀性、抗菌性及韧性,被广泛应用于航空航天、交通运输、电子、医疗和能源动力等领域。随着零部件轻量化、复杂化和结构功能一体化需求的提高,传统铸造、锻造及切削加工在复杂结构成形、材料利用率和制造周期等方面逐渐受限。增材制造(AM)技术可基于三维模型实现铜基构件逐层成形,为复杂内腔、随形冷却通道及功能梯度构件制造提供新途径。本文总结了铜基材料增材制造的研究进展,重点分析了激光粉末床熔融、电子束粉末床熔融、定向能量沉积、粉末挤出和黏结剂喷射等技术的原理、特点,以及成形过程中易产生的孔隙、裂纹、未熔合和组织不均匀等缺陷;总结了工艺优化、粉末改性、合金化设计、热处理和热等静压等调控策略,最后,展望了铜基材料增材制造在材料体系拓展、在线监测、标准化评价及工业化应用等方面的未来发展方向,以期为结构功能一体化铜基构件的高质量制造提供参考。

Abstract

Copper-based materials are widely used in aerospace, transportation, electronics, medical, and energy power fields due to their excellent electrical conductivity, thermal conductivity, ductility, corrosion resistance, antibacterial properties, and toughness. With the increasing demand for lightweight, complexity, and integrated structural and functional components, traditional casting, forging, and cutting processes are gradually being limited in areas such as forming complex structures, material utilization, and manufacturing cycles. Additive manufacturing (AM) technology can achieve layer-by-layer forming of copper-based components based on 3D models, providing new approaches for manufacturing complex internal cavities, conformal cooling channels, and functionally gradient components. The work aims to review the research progress in additive manufacturing of copper-based materials, with a focus on the principles and characteristics of laser powder bed fusion, electron beam powder bed fusion, directed energy deposition, powder extrusion, and binder jetting, as well as typical defects arising during fabrication, including pores, cracks, lack of fusion, and microstructural inhomogeneity. Strategies for improving the forming quality and material properties, including process optimization, powder modification, alloying design, heat treatment, and hot isostatic pressing, are summarized. Finally, the future development directions of additive manufacturing of copper-based materials in areas such as material system expansion, online monitoring, standardization evaluation, and industrial application are discussed, aiming to provide a reference for high-quality manufacturing of integrated copper-based components with integrated structural functions.

关键词

铜基材料 / 增材制造 / 组织调控 / 力学性能 / 结构功能一体化

Key words

copper-based materials / additive manufacturing / microstructure regulation / mechanical properties / integrated structural functions

引用本文

导出引用
牛敬涵, 邓海亮, 王沛, 郭利萍, 梁士杰, 蔡嘉伟, 付志强, 徐继福. 增材制造铜基材料的工艺、组织与性能研究进展[J]. 精密成形工程. 2026, 18(8): 14-33 https://doi.org/10.3969/j.issn.1674-6457.2026.08.002
NIU Jinghan, DENG Hailiang, WANG Pei, GUO Liping, LIANG Shijie, CAI Jiawei, FU Zhiqiang, XU Jifu. Research Progress on the Process, Microstructure, and Properties of Additively Manufactured Copper-based Materials[J]. Journal of Netshape Forming Engineering. 2026, 18(8): 14-33 https://doi.org/10.3969/j.issn.1674-6457.2026.08.002
中图分类号: TG146.1+1   

参考文献

[1] ZHANG C, WANG S, LI J, et al.Additive Manufacturing of Products with Functional Fluid Channels: A Review[J]. Additive Manufacturing, 2020, 36: 101490.
[2] MOSTAFAEI A, ELLIOTT A M, BARNES J E, et al.Binder Jet 3D Printing—Process Parameters, Materials, Properties, Modeling, and Challenges[J]. Progress in Materials Science, 2021, 119: 100707
[3] 刘劲松, 汤旭晶, 王松伟, 等. 铜铬系合金研究和发展现状[J]. 铜业工程, 2023(4): 39-51.
LIU J S, TANG X J, WANG S W, et al.Research and Development Status of Cu-Cr Alloys[J]. Copper Engineering, 2023(4): 39-51.
[4] 辛嘉木, 范林, 刘亚鹏, 等. 铜及其合金在海洋环境中的腐蚀机理研究进展[J]. 装备环境工程, 2024, 21(10): 127-136.
XIN J M, FAN L, LIU Y P, et al.Research Progress on the Corrosion Mechanism of Copper and Its Alloys in Marine Environment[J]. Equipment Environmental Engineering, 2024, 21(10): 127-136.
[5] BLAKEY-MILNER B, GRADL P, SNEDDEN G, et al.Metal Additive Manufacturing in Aerospace: A Review[J]. Materials & Design, 2021, 209: 110008.
[6] FAVERO G, BONESSO M, DIMA R, et al.Effect of the Building Orientation on Additively Manufactured Copper Alloy: Hydraulic Performance of Different Surface Roughness Channels[J]. International Journal of Thermofluids, 2024, 23: 100790.
[7] GÜNTHER I, ZILLMANN B, NIENDORF T. Metal Powder Bed Fusion of Pure and Coated Copper for Power Electronics Applications Using a Green Laser[J]. Journal of Materials Research and Technology, 2025, 38: 5250-5262.
[8] WANG Y G, LI H Y, YUAN X Y, et al.Review of Copper and Copper Alloys as Immune and Antibacterial Element[J]. Transactions of Nonferrous Metals Society of China, 2022, 32(10): 3163-3181.
[9] CANILLAS F, LEON-GUTIERREZ E, ROLDAN M, et al.On the Feasibility to Obtain CuCrZr Alloys with Outstanding Thermal and Mechanical Properties by Additive Manufacturing[J]. Journal of Nuclear Materials, 2024, 601: 155304.
[10] ZHAO J, ZHANG B G, LI X P, et al.Effects of Metal-Vapor Jet Force on the Physical Behavior of Melting Wire Transfer in Electron Beam Additive Manufacturing[J]. Journal of Materials Processing Technology, 2015, 220: 243-250.
[11] DAI G Q, SUN Z G, LI Y S, et al.Grain Refinement and Columnar-to-Equiaxed Transition of Ti6Al4V during Additive Manufacturing via Different Laser Oscillations[J]. International Journal of Machine Tools and Manufacture, 2023, 189: 104031.
[12] LEE H, RASMUSSEN M J, NIMLOS C T, et al.Powders and Pellets-Extrusion Engineering for a Cu/BEA Syngas-to-Hydrocarbons Catalyst[J]. Applied Catalysis B: Environment and Energy, 2026, 387: 126464.
[13] DAHMEN T, HENRIKSEN N G, DAHL K V, et al.Densification, Microstructure, and Mechanical Properties of Heat-Treated MAR-M247 Fabricated by Binder Jetting[J]. Additive Manufacturing, 2021, 39: 101912.
[14] 深圳升华三维科技有限公司. 粉末挤出打印技术(PEP)简介[EB/OL][2026-04-27].https://www.uprise3d.cn/.
Shenzhen Uprise 3D Technology Co., Ltd.Introduction to Powder Extrusion Printing (PEP)[EB/OL].[2026-04-27]. https://www.uprise3d.cn/.
[15] ZHANG R Z, FANG J Y, GUO Y M, et al.Effect of Direct Aging Heat Treatment on Microstructures and Properties of CuCrZr Alloy Manufactured by Laser Powder Bed Fusion[J]. Journal of Materials Research and Technology, 2025, 36: 8591-8601.
[16] TANG X P, CHEN X H, SUN F J, et al.A Study on the Mechanical and Electrical Properties of High-Strength CuCrZr Alloy Fabricated Using Laser Powder Bed Fusion[J]. Journal of Alloys and Compounds, 2022, 924: 166627.
[17] SCHÄFLE M B, GÄRTNER J, NAHR F, et al. Process Development for Green Laser LPBF of Pure Cu Using Dimensionless Numbers[J]. Progress in Additive Manufacturing, 2025, 10(10): 8179-8196.
[18] TERTULIANO O A, DEPOND P J, LEE A C, et al. High Absorptivity Nanotextured Powders for Additive Manufacturing[J]. Science Advances, 2024, 10(36): eadp0003.
[19] BHATT B, MARTUCCI A, BIAMINO S, et al.Current Trends in Electron Beam and Laser Powder Bed Fusion Additive Manufacturing of Copper Alloys: Composition, Defects, Properties, and Challenges[J]. Materials & Design, 2025, 253: 113742.
[20] JAVIDRAD H, KOC B.Toward the Process Parameters Optimization and Characterization of CuCrZr Alloy Processed via the Directed Energy Deposition Method[J]. Progress in Additive Manufacturing, 2026, 11(3): 3027-3043.
[21] MOSTAFAEI A, ELLIOTT A M, BARNES J E, et al.Binder Jet 3D Printing—Process Parameters, Materials, Properties, Modeling, and Challenges[J]. Progress in Materials Science, 2021, 119: 100707.
[22] ARMSTRONG M, MEHRABI H, NAVEED N.An Overview of Modern Metal Additive Manufacturing Technology[J]. Journal of Manufacturing Processes, 2022, 84: 1001-1029.
[23] AHN D G. Directed Energy Deposition (DED) Process: State of the Art[J]. International Journal of Precision Engineering and Manufacturing-Green Technology, 2021, 8(2): 703-742.
[24] CHOWDHURY S, YADAIAH N, PRAKASH C, et al.Laser Powder Bed Fusion: A State-of-the-Art Review of the Technology, Materials, Properties & Defects, and Numerical Modelling[J]. Journal of Materials Research and Technology, 2022, 20: 2109-2172.
[25] JIANG Q, ZHANG P L, YU Z S, et al.A Review on Additive Manufacturing of Pure Copper[J]. Coatings, 2021, 11(6): 740.
[26] AGHAYAR Y, MOAZZEN P, KESTENS L A I, et al. Tailoring the Microstructure, Physical, and Mechanical Properties of Pure Copper Using Various Additive Manufacturing Techniques[J]. Journal of Alloys and Compounds, 2025, 1010: 178332.
[27] GRUBER S, STEPIEN L, GERDT L, et al.Process Development for Laser Powder Bed Fusion of GRCop-42 Using a 515 nm Laser Source[J]. Journal of Laser Applications, 2023, 35(4): 042078.
[28] ZHANG X R, GAO J B, ZHANG J L, et al.Mechanism of Simultaneous Improvement of Mechanical Performance and Conductivity of TiC/Cu Composites Prepared by Laser Powder Bed Fusion[J]. Journal of Alloys and Compounds, 2024, 1002: 175281.
[29] THOMAS A, FRIBOURG G, BLANDIN J J, et al.Effect of the Build Orientation on Mechanical and Electrical Properties of Pure Cu Fabricated by E-PBF[J]. Additive Manufacturing, 2021, 48: 102393.
[30] YAN Q B, LI Y Z, WEI Y K, et al.Superior Strength-Ductility-Conductivity Synergy of GRCop-42 Alloy Manufactured via Electron Beam Powder Bed Fusion[J]. Journal of Materials Research and Technology, 2026, 40: 1202-1212.
[31] LI Y Z, LIU S F, YAN Q B, et al.Achieving High Strength, High Ductility and High Conductivity of Additively Manufactured CuCrZr Alloy via Control of Powder Bed Temperature[J]. Materials Science and Engineering: A, 2025, 930: 148114.
[32] ORTMANN R, ZIESING U, BALACHANDRAMURTHI A, et al.Powder Bed Fusion of Pure Copper Using an Electron Beam: A Comparative Study on the Material Properties Obtained Using Vector-and Spot-Based Exposure[J]. Progress in Additive Manufacturing, 2025, 10(12): 10487-10503.
[33] YADAV S, PAUL C P, JINOOP A N, et al.Laser Directed Energy Deposition Based Additive Manufacturing of Copper: Process Development and Material Characterizations[J]. Journal of Manufacturing Processes, 2020, 58: 984-997.
[34] MA W J, WANG Y F, PANG Y H, et al.Enhanced Strength and Ductility in Laser Powder Bed Fusion of Cu-Cr-Zr-Based Composite Reinforced by Micro-Nano Dual-Scale Borides[J]. Virtual and Physical Prototyping, 2026, 21(1): e2653279.
[35] ALDEITURRIAGA N, FRAILE I, DOMINGUEZ E, et al.Effect of Material Extrusion Method on the Microstructure and Mechanical Properties of Copper Parts[J]. Metals, 2024, 14(8): 941.
[36] YEGYAN KUMAR A, WANG J, BAI Y, et al.Impacts of Process-Induced Porosity on Material Properties of Copper Made by Binder Jetting Additive Manufacturing[J]. Materials & Design, 2019, 182: 108001.
[37] KUAI Z Z, LI Z H, LIU B, et al.Selective Laser Melting of CuCrZr Alloy: Processing Optimisation, Microstructure and Mechanical Properties[J]. Journal of Materials Research and Technology, 2022, 19: 4915-4931.
[38] CRAWFORD N K, DEISENROTH D, GONZALEZ L D, et al.Ultra-High Speed Printing Regime in Laser Powder Bed Fusion of Highly Reflective Metals[J]. Additive Manufacturing, 2026, 121: 105142.
[39] JADHAV S D, VLEUGELS J, KRUTH J P, et al.Mechanical and Electrical Properties of Selective Laser-Melted Parts Produced from Surface-Oxidized Copper Powder[J]. Material Design & Processing Communications, 2020, 2(2): e94.
[40] YANG P, GUO X Y, HE D Y, et al.Selective Laser Melting of High Relative Density and High Strength Parts Made of Minor Surface Oxidation Treated Pure Copper Powder[J]. Metals, 2021, 11(12): 1883.
[41] LIU Q, REN C X, SONG Z Z, et al.High-Strength and High-Conductivity Additively Manufactured Cu-O Alloy Enabled by Cellular Microstructure[J]. Additive Manufacturing, 2024, 88: 104244.
[42] KUAI Z Z, LI Z H, LIU B, et al.Effect of Heat Treatment on CuCrZr Alloy Fabricated by Selective Laser Melting: Microstructure Evolution, Mechanical Properties and Fracture Mechanism[J]. Journal of Materials Research and Technology, 2023, 23: 2658-2671.
[43] MAO Z F, ZHANG D Z, JIANG J J, et al.Processing Optimisation, Mechanical Properties and Microstructural Evolution during Selective Laser Melting of Cu-15Sn High-Tin Bronze[J]. Materials Science and Engineering: A, 2018, 721: 125-134.
[44] PADDOCK-LAMB R, KHANBOLOUKI P, CULLINAN M A, et al.Near-Infrared Laser Powder Bed Fusion of Pure Copper: Post-Processing and Structure-Property Relationships[J]. Journal of Materials Research and Technology, 2026, 40: 1665-1673.
[45] DU PLESSIS A, YELAMANCHI B, FISCHER C, et al.Productivity Enhancement of Laser Powder Bed Fusion Using Compensated Shelled Geometries and Hot Isostatic Pressing[J]. Advances in Industrial and Manufacturing Engineering, 2021, 2: 100031.
[46] LI J K, CHENG T, LIU Y B, et al.Simultaneously Enhanced Strength and Ductility of Cu-15Ni-8Sn Alloy with Periodic Heterogeneous Microstructures Fabricated by Laser Powder Bed Fusion[J]. Additive Manufacturing, 2022, 54: 102726.
[47] BAMBACH M, TUCKER M R.Laser Powder Bed Fusion of Planar Bi-Metallic Thermally Auxetic Lattice Structures[J]. CIRP Annals, 2024, 73(1): 141-144.
[48] LI Y Z, LIU S F, WANG Y, et al.Effect of Electron Beam Energy Density on the Microstructure and Properties of CuCrZr Alloy Prepared by Electron Beam Powder Bed Fusion (EB-PBF)[J]. Materials Characterization, 2024, 214: 114031.
[49] GUSCHLBAUER R, BURKHARDT A K, FU Z W, et al.Effect of the Oxygen Content of Pure Copper Powder on Selective Electron Beam Melting[J]. Materials Science and Engineering: A, 2020, 779: 139106.
[50] OVALLE D G, ROCK C, WINKLER C, et al.Microstructure Development and Properties of Micro-Alloyed Copper, Cu-0.3Zr-0.15Ag, Produced by Electron Beam Additive Manufacturing[J]. Materials Characterization, 2023, 197: 112675.
[51] HOMAS A, GUILLAUME F, BLANDIN J J, et al.Tailoring the Crystallographic Texture of Pure Copper Through Control of the Scanning Strategy in Electron Powder Bed Fusion[J]. 2022.
[52] 李长富, 杜炳鑫, 李晓丹, 等. 激光定向能量沉积Cu/Al复合材料的显微组织和维氏硬度[J]. 材料工程, 2025, 53(10): 132-141.
LI C F, DU B X, LI X D, et al.Microstructure and Microhardness of Laser Directed Energy Deposition of Cu/Al Composites[J]. Journal of Materials Engineering, 2025, 53(10): 132-141.
[53] THANUMOORTHY R S, SHARMA S, BONTHA S, et al.Laser Powder-Directed Energy Deposition of CuCrZr Using Increasing LEPF Approach: Process Development and Characterization for Mechanical and Thermal Properties[J]. Progress in Additive Manufacturing, 2025, 10(8): 5601-5621.
[54] OTYNSHIYEV Y, SARIYEV B, GOLMAN B, et al.Wire-and Powder-Based Direct Energy Deposition of NiTi-CuSn10-SS316L[J]. Materials and Manufacturing Processes, 2025, 40(8): 1049-1058.
[55] AN Y D, DONG Q, YU S L, et al.Investigation on Local Dissolution and Anti-Corrosion Characteristic of Directed Energy Deposition (DED) CoCrMo-xCu Alloys in Marine Environment[J]. Corrosion Science, 2025, 256: 113176.
[56] MALEC W, KULASA J, BRUDNY A, et al.Comparative Studies of the Properties of Copper Components: Conventional Vs. Additive Manufacturing Technologies[J]. Metals, 2024, 14(9): 975.
[57] RAHMAN K M, WEI A, MIYANAJI H, et al.Impact of Binder on Part Densification: Enhancing Binder Jetting Part Properties through the Fabrication of Shelled Geometries[J]. Additive Manufacturing, 2023, 62: 103377.
[58] BAI Y, WILLIAMS C B.Binder Jetting Additive Manufacturing with a Particle-Free Metal Ink as a Binder Precursor[J]. Materials & Design, 2018, 147: 146-156.
[59] ROMANO T, MIGLIORI E, MARIANI M, et al.Densification Behaviour of Pure Copper Processed through Cold Pressing and Binder Jetting under Different Atmospheres[J]. Rapid Prototyping Journal, 2022, 28(6): 1023-1039.
[60] MIYANAJI H, MA D, ATWATER M A, et al.Binder Jetting Additive Manufacturing of Copper Foam Structures[J]. Additive Manufacturing, 2020, 32: 100960.
[61] PERVAN D, BASTOLA A, WORSLEY R, et al.Additive Manufacturing of Electrically Conductive Multi-Layered Nanocopper in an Air Environment[J]. Nanomaterials, 2024, 14(9): 753.
[62] LI W Y, LI C J, LIAO H L.Significant Influence of Particle Surface Oxidation on Deposition Efficiency, Interface Microstructure and Adhesive Strength of Cold-Sprayed Copper Coatings[J]. Applied Surface Science, 2010, 256(16): 4953-4958.
[63] MARIANI M, BERTOLINI F, FABIOCCHI L, et al.Alumina-Based Interpenetrating Phase Composites by Binder Jetting: Effects of Powder Multimodal Distributions on Porous Preforms Formation and Copper-Infiltrated Composite Performance[J]. Materials Characterization, 2025, 229: 115651.
[64] MORSHED-BEHBAHANI K, ALIYU A, BISHOP D P, et al.Additive Manufacturing of Copper-Based Alloys for High-Temperature Aerospace Applications: A Review[J]. Materials Today Communications, 2024, 38: 108395.
[65] 华曙高科. Farsoon Unveils Large-Scale, Production-Grade Copper Alloy Additive Manufacturing Solution FS621M-Cu[EB/OL]. (2025-06-16)[2026-04-27] https://www.farsoon-gl.com/news/farsoon-unveils-large-scale-production-grade-copper-alloy-additive-manufacturing-solution-fs621m-cu/.
Farsoon Technologies. Farsoon Unveils Large-Scale, Production-Grade Copper Alloy Additive Manufacturing Solution FS621M-Cu[EB/OL]. (2025-06-166)[2026-04-27]. https://www.farsoon-gl.com/news/farsoon-unveils-large-scale-production-grade-copper-alloy-additive-manufacturing-solution-fs621m-cu/.
[66] ZHANG Y K, XU L Y, ZHAO L, et al.Deformation Mechanism of Cu-Al-Ni Shape Memory Alloys Fabricated via Laser Powder Bed Fusion: Tension-Compression Asymmetry[J]. Journal of Materials Science & Technology, 2023, 167: 14-26.
[67] 西安铂力特增材技术股份有限公司. A New Approach to Rocket Engine Cooling: BLT 3D Printed Copper Thrust Chamber Part[EB/OL]. (2025-12-03)[2026-04-27].https://www.xa-blt.com/en/news/a-new-approach-to-rocket-engine-cooling%EF%BC%9Ablt-3d-printed-copper-thrust-chamber-part/.
Xi'an Bright Laser Technologies Co., Ltd. A New Approach to Rocket Engine Cooling: BLT 3D Printed Copper Thrust Chamber Part[EB/OL]. (2025-12-03)[2026-04-27]. https://www.xa-blt.com/en/news/a-new-approach-to-rocket-engine-cooling%EF%BC%9Ablt-3d-printed-copper-thrust-chamber-part/.
[68] ALEIXO D D, FIRDAOUSS M, BAFFIE T, et al.Promising Cooling Concepts for Enhanced JT-60SA Tungsten Actively Cooled Divertor[J]. Nuclear Materials and Energy, 2025, 45: 102030.
[69] NASA. National Aeronautics and Space Administration.A One-piece Liquid Rocket Thrust Chamber Assembly[EB/OL].[2026-04-27]. https://technology.nasa.gov/patent/MFS-TOPS-93.
[70] AL-KETAN O.Additive Manufacturing-Assisted Casting of 3D Micro-Architected Heat Sinks[J]. Materials Letters, 2025, 379: 137641.
[71] KANG S G, GAINOV R, HEUßEN D, et al. Green Laser Powder Bed Fusion Based Fabrication and Rate-Dependent Mechanical Properties of Copper Lattices[J]. Materials & Design, 2023, 231: 112023.
[72] SHIN S, JEON I, SOHN H.Enhanced Geometric Accuracy in Directed Energy Deposition via Closed-Loop Melt Pool Height Control Using Real-Time Thermal Imaging[J]. Additive Manufacturing, 2025, 109: 104846.
[73] DEMENEGHI G, GRADL P, MAYEUR J R, et al.Size Effect Characteristics and Influences on Fatigue Behavior of Laser Powder Bed Fusion of Thin Wall GRCop-42 Copper Alloy[J]. Heliyon, 2024, 10(7): e28679.

PDF(53548 KB)

Accesses

Citation

Detail

段落导航
相关文章

/