含Si-Al中碳钢Mf点淬火等温马氏体相变行为及其超高韧性机理

胡锋, 王同良, 王坤, 邱保文

精密成形工程 ›› 2026, Vol. 18 ›› Issue (4) : 136-146.

PDF(15575 KB)
PDF(15575 KB)
精密成形工程 ›› 2026, Vol. 18 ›› Issue (4) : 136-146. DOI: 10.3969/j.issn.1674-6457.2026.04.014
钢铁成形

含Si-Al中碳钢Mf点淬火等温马氏体相变行为及其超高韧性机理

  • 胡锋1,2,3, 王同良1,2,4,*, 王坤3, 邱保文1,2,4
作者信息 +

Martensitic Transformation Behavior and Ultra-high Toughness Mechanism of Mf Point Quenching Isothermal in the Medium Carbon Steel Containing Si-Al

  • HU Feng1,2,3, WANG Tongliang1,2,4,*, WANG Kun3, QIU Baowen1,2,4
Author information +
文章历史 +

摘要

目的 针对传统中碳钢高强度与超高韧性难以协同提升的问题,以含Si-Al中碳钢为研究对象,系统对比传统淬火回火(QT)与新型Mf点淬火等温(QI)工艺,揭示Mf点(200 ℃)等温相变行为对材料强韧性的影响机制;通过调控等温时间优化碳配分效应与残余奥氏体稳定性,以开发兼具高强度与超高韧性的结构钢。方法 利用OM、SEM观察显微组织,通过TEM分析板条宽度与残余奥氏体形态,通过XRD计算残余奥氏体碳含量,并通过拉伸与冲击试验评价力学性能。结果 在QT工艺下,显微组织为回火马氏体与ε-碳化物;而QI工艺通过碳配分效应形成等温马氏体/高碳残余奥氏体(1.46%)片层结构,残余奥氏体体积分数稳定在5.5%,等温马氏体板条平均宽度降至(216±95) nm(较QT细化42.7%)。QI200-32的冲击吸收功>130 J,是QT200-32的2.7倍,同时保持1 436 MPa的抗拉强度,实现了高强度与超高韧性的协同提升。结论 突破了传统QT工艺的强韧性倒置限制,Mf点淬火等温工艺通过碳配分主导的相变机制调控马氏体和残留奥氏体双相组织,超高韧性归因于等温马氏体板条细化显著提升了位错阻碍效应,以及高碳残余奥氏体薄膜通过TRIP效应吸收塑性变形功,偏转与钝化裂纹。本研究为开发高强度-超高韧性中碳钢提供了新思路,通过调控Mf点淬火等温相变行为,优化片层组织与碳配分设计,可显著改善材料的抗断裂性能。

Abstract

In response to the bottleneck problem of difficult synergistic improvement of high strength and ultra-high toughness in traditional medium carbon steel, the work aims to take the medium carbon steel containing Si-Al as the object, to systematically compare the traditional quenching and tempering (QT) with the new Mf point quenching isothermal (QI) process, and reveal the effect mechanism of Mf point (200 ℃) isothermal phase transformation behavior on material strength and toughness, so as to develop structural steels that combine high strength and ultra-high toughness by adjusting the isothermal time to optimize the carbon distribution effect and retained austenite stability. The microstructure was observed through OM and SEM, the width of lath and the morphology of retained austenite were analyzed by TEM, the carbon content of retained austenite was calculated by XRD, and the mechanical properties were evaluated by tensile and impact tests. The microstructure under QT process consisted of tempered martensite and ε-carbides. However, the QI process formed a lamellar structure of isothermal martensite/high carbon retained austenite (1.46%) through carbon partition effect, the volume fraction of retained austenite was stabilized at 5.5%, and the average width of isothermal martensite lath was reduced to (216±95) nm (42.7% finer than QT). The impact absorption energy of QI200-32 reached >130 J, which was 2.7 times that of QT200-32, while a tensile strength of 1 436 MPa was maintained, achieving a synergistic improvement of high strength and ultra-high toughness. The study breaks through the inversion limit of strength and toughness of the traditional QT process, and the Mf point quenching isothermal process regulates the dual phase structure (martensite and retained austenite) through the transformation mechanism dominated by carbon distribution. The ultra-high toughness is attributed to the refinement of isothermal martensite lath, which significantly improves the dislocation blocking effect, and the high carbon retained austenite film absorbs plastic deformation work, deflects and passivates cracks through the TRIP effect. This study provides a new approach for the development of high-strength and ultra-high toughness medium carbon steel. By regulating the isothermal phase transformation behavior of Mf point quenching and optimizing the layer structure and carbon distribution design, the fracture resistance of the material can be significantly improved.

关键词

含Si-Al中碳钢 / Mf点淬火等温 / 马氏体相变 / 残余奥氏体 / 韧性机理

Key words

medium carbon steel containing Si-Al / Mf point quenching isothermal / martensitic transformation / retained austenite / toughness mechanism

引用本文

导出引用
胡锋, 王同良, 王坤, 邱保文. 含Si-Al中碳钢Mf点淬火等温马氏体相变行为及其超高韧性机理[J]. 精密成形工程. 2026, 18(4): 136-146 https://doi.org/10.3969/j.issn.1674-6457.2026.04.014
HU Feng, WANG Tongliang, WANG Kun, QIU Baowen. Martensitic Transformation Behavior and Ultra-high Toughness Mechanism of Mf Point Quenching Isothermal in the Medium Carbon Steel Containing Si-Al[J]. Journal of Netshape Forming Engineering. 2026, 18(4): 136-146 https://doi.org/10.3969/j.issn.1674-6457.2026.04.014
中图分类号: TG1   

参考文献

[1] 范长刚, 董瀚, 雍岐龙, 等. 低合金超高强度钢的研究进展[J]. 机械工程材料, 2006, 30(8): 1-4.
FAN C G, DONG H, YONG Q L, et al.Research Development of Ultra-High Strength Low Alloy Steels[J]. Materials for Mechanical Engineering, 2006, 30(8): 1-4.
[2] ZHAO J W, JIANG Z Y.Thermomechanical Processing of Advanced High Strength Steels[J]. Progress in Materials Science, 2018, 94: 174-242.
[3] DE COOMAN B C. Structure-Properties Relationship in TRIP Steels Containing Carbide-Free Bainite[J]. Current Opinion in Solid State and Materials Science, 2004, 8(3/4): 285-303.
[4] CABALLERO F G, CHAO J, CORNIDE J, et al.Toughness Deterioration in Advanced High Strength Bainitic Steels[J]. Materials Science and Engineering: A, 2009, 525(1/2): 87-95.
[5] CABALLERO F G, SANTOFIMIA M J, GARCÍA-MATEO C, et al. Theoretical Design and Advanced Microstructure in Super High Strength Steels[J]. Materials & Design, 2009, 30(6): 2077-2083.
[6] GONG W, TOMOTA Y, HARJO S, et al.Effect of Prior Martensite on Bainite Transformation in Nanobainite Steel[J]. Acta Materialia, 2015, 85: 243-249.
[7] SAMANTA S, BISWAS P, GIRI S, et al.Formation of Bainite below the Ms Temperature: Kinetics and Crystallography[J]. Acta Materialia, 2016, 105: 390-403.
[8] ZHAO L J, QIAN L H, MENG J Y, et al.Below-Ms Austempering to Obtain Refined Bainitic Structure and Enhanced Mechanical Properties in Low-C High-Si/Al Steels[J]. Scripta Materialia, 2016, 112: 96-100.
[9] ZHAO L J, QIAN L H, ZHOU Q, et al.The Combining Effects of Ausforming and Below-Ms or Above-Ms Austempering on the Transformation Kinetics, Microstructure and Mechanical Properties of Low-Carbon Bainitic Steel[J]. Materials & Design, 2019, 183: 108123.
[10] XIA S L, ZHANG F C, YANG Z N.Cyclic Deformation Behaviours of 18Mn3Si2CrNiMo Multiphase (Martensite/Bainite/Retained Austensite) Steel[J]. Materials Science and Engineering: A, 2019, 744: 64-73.
[11] WANG K, HU F, ZHOU S B, et al.Microstructural Evolution and Ultra-High Impact Toughness of Austempered Lamellar Bainitic Steel far below Ms Temperature[J]. Journal of Materials Research and Technology, 2023, 24: 5449-5462.
[12] WANG K, HU F, ZHOU W, et al.Effect of Refined Multi-Scale Microstructures on the Ultra-High Impact Toughness of Bainitic Steel Austempered below ms Temperature[J]. Journal of Materials Research and Technology, 2023, 26: 5773-5785.
[13] WANG K, HU F, ZHOU S B, et al.Effect of Microstructure Transformation below Ms Temperature in Bainitic Steels on the Impact-Abrasive Wear Behavior[J]. Wear, 2023, 514: 204589.
[14] WANG K, HU F, ZHOU S B, et al.Ultrahigh Impact Toughness Achieved in High Strength Bainitic Ferrite/Retained Austenite Lamellar Steels Below-Mf Temperature[J]. Materials Letters, 2022, 324: 132517.
[15] AVISHAN B, YAZDANI S, NEDJAD S H.Toughness Variations in Nanostructured Bainitic Steels[J]. Materials Science and Engineering: A, 2012, 548: 106-111.
[16] BHADESHIA H K D H. Nanostructured Bainite[J]. Proceedings of the Royal Society A, 2010, 466: 3-18.
[17] GARCIA-MATEO C, CABALLERO F G.Ultra-High-Strength Bainitic Steels[J]. ISIJ International, 2005, 45(11): 1736-1740.
[18] KUMAR A, SINGH A.Toughness Dependence of Nano-Bainite on Phase Fraction and Morphology[J]. Materials Science and Engineering: A, 2018, 729: 439-443.
[19] KUMAR A, SINGH A.Improvement of Strength-Toughness Combination in Nanostructured Bainite[J]. Procedia Structural Integrity, 2018, 13: 548-553.
[20] BHADESHIA H K D H. Bainite in Steels: Theory and Practice[M]. London: CRC Press, 2015.
[21] CHEN A Y, LI D F, ZHANG J B, et al.Make Nanostructured Metal Exceptionally Tough by Introducing Non-Localized Fracture Behaviors[J]. Scripta Materialia, 2008, 59(6): 579-582.
[22] SPEER J G, EDMONDS D V, RIZZO F C, et al.Partitioning of Carbon from Supersaturated Plates of Ferrite, with Application to Steel Processing and Fundamentals of the Bainite Transformation[J]. Current Opinion in Solid State and Materials Science, 2004, 8(3/4): 219-237.
[23] GARCÍA-MATEO C, CABALLERO F G, BHADESHIA H K D H. Mechanical Properties of Low-Temperature Bainite[J]. Materials Science Forum, 2005, 500/501: 495-502.
[24] 周超, 黄军, 马东亮, 等. 新型马氏体耐热钢蠕变-疲劳断裂机制及微观损伤行为研究[J]. 精密成形工程, 2025, 17(7): 110-118.
ZHOU C, HUANG J, MA D L, et al.Creep-Fatigue Fracture Mechanism and Microscopic Damage Behavior of New Martensitic Heat-Resistant Steel[J]. Journal of Netshape Forming Engineering, 2025, 17(7): 110-118.
[25] 田亚强, 张宏军, 陈连生, 等. 低碳高强钢合金元素配分行为对残余奥氏体和力学性能的影响[J]. 金属学报, 2014, 50(5): 531-539.
TIAN Y Q, ZHANG H J, CHEN L S, et al.Effect of Alloy Elements Partitioning Behavior on Retained Austenite and Mechanical Property in Low Carbon High Strength Steel[J]. Acta Metallurgica Sinica, 2014, 50(5): 531-539.
[26] ZHANG K, ZHANG M H, GUO Z H, et al.A New Effect of Retained Austenite on Ductility Enhancement in High-Strength Quenching-Partitioning-Tempering Martensitic Steel[J]. Materials Science and Engineering: A, 2011, 528(29/30): 8486-8491.
[27] WANG Y, ZHANG K, GUO Z H, et al.A New Effect of Retained Austenite on Ductility Enhancement in High Strength Bainitic Steel[J]. Materials Science and Engineering: A, 2012, 552: 288-294.
[28] TIMOKHINA I B, HODGSON P D, PERELOMA E V.Effect of Microstructure on the Stability of Retained Austenite in Transformation-Induced-Plasticity Steels[J]. Metallurgical and Materials Transactions A, 2004, 35(8): 2331-2341.
[29] 苏钰, 符仁钰, 李麟, 等. 低碳含硅TRIP钢断裂机理的研究[J]. 上海大学学报(自然科学版), 2006, 12(4): 423-427.
SU Y, FU R Y, LI L, et al.Fracture Mechanism of Low Carbon TRIP Steel with Si[J]. Journal of Shanghai University (Natural Science Edition), 2006, 12(4): 423-427.
[30] 张梅. 高强度和超高强度相变塑性钢的开发和研究[D]. 上海: 上海大学, 2007.
ZHANG M.Study on new high strength and super high strength TRIP steels[D]. Shanghai: Shanghai University, 2007.
[31] 王坤. Ms温度以下等温淬火中碳低合金钢微观结构调控与关键机械性能研究[D]. 武汉: 武汉科技大学, 2024.
WANG K.Study on Microstructure Control and Key Mechanical Properties of Austempered Medium Carbon Low-alloy Steel Below Ms Temperature[D]. Wuhan: Wuhan University of Science and Technology, 2024.

基金

河南省重大科技专项(251100230200)

PDF(15575 KB)

Accesses

Citation

Detail

段落导航
相关文章

/