目的 采用CMT电弧增材制造技术,在高强度模具钢表面构建具有梯度过渡特征的高强耐磨复合熔覆层,旨在提升模具钢表面硬度与耐磨性能,从而延长模具的使用寿命。方法 基于CMT电弧增材制造技术,通过选择合适的焊接材料设计出具有硬度梯度过渡的复合熔覆层。以通用的H13模具钢为基材,采用FK1000焊丝作为中间过渡层、YD322焊丝作为高强耐磨层进行逐层熔覆,以达到硬度和韧性梯度过渡的目的。结果 对熔覆后的复合材料进行微观组织和力学性能研究,结果表明,熔覆试样宏观成形良好,无明显冶金缺陷。高强耐磨层主要由细小的板条马氏体以及残余奥氏体组成,过渡层主要为贝氏体及铁素体,二次受热区和热影响区均有回火组织出现。该复合熔覆层从基材到过渡层再到高强耐磨层硬度呈梯度式提升,硬度逐级升高。该复合材料硬度从基材的248HV提升至耐磨层的581HV,硬度提高了135%。冲击韧性较基材略有下降,从基材的12 J下降到复合试样的9.3 J,其断裂方式为解理断裂。耐磨层的磨损质量为1.3 mg,磨损系数为0.365,与基材相比,磨损质量减少了69.7%,平均磨损系数从0.43降低至0.365。
Abstract
The work aims to study the formation of a gradient transition high-strength wear-resistant layer on the surface of high-strength die steel by CMT arc additive manufacturing, so as to obtain a composite cladding layer to improve the surface hardness and wear resistance and prolong the service life of the die. Based on CMT arc additive manufacturing technology, a composite cladding layer with hardness gradient transition was designed by selecting appropriate welding materials. With the general H13 die steel as the substrate, FK1000 welding wires were used as the intermediate transition layer, and YD322 welding wires were used as the high-strength wear-resistant layer for layer-by-layer cladding to achieve the purpose of gradient transition of hardness and toughness. The microstructure and mechanical properties of the composites after cladding were studied. The results showed that the macroscopic forming of the cladding samples was good and there were no obvious metallurgical defects. The high-strength wear-resistant layer was mainly composed of fine lath martensite and retained austenite. The transition layer was mainly bainite and ferrite, and the tempering structure appeared in the secondary heating zone and the heat-affected zone. The hardness of the composite cladding layer from the substrate to the transition layer to the high-strength wear-resistant layer was gradient, and the hardness increased step by step. The hardness of the composite increased from 248HV of the substrate to 581HV of the wear-resistant layer, and the hardness increased by 135%. The impact toughness decreased slightly from 12 J of the substrate to 9.3 J of the composite sample. And the fracture mode was cleavage fracture. The wear mass of the wear-resistant layer was 1.3 mg, and the wear coefficient was 0.365. Compared with the substrate, the wear mass was reduced by 69.7%, and the average wear coefficient was reduced from 0.43 to 0.365.
关键词
电弧增材制造(WAAM) /
CMT熔覆 /
H13模具钢 /
梯度过渡 /
高强耐磨层
Key words
CMT welding /
wire arc additive manufacturing /
H13 die steel /
gradient transition /
high-strength wear-resistant layer
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参考文献
[1] 伊浩, 黄如峰, 曹华军, 等. 基于CMT的钛合金电弧增材制造技术研究现状与展望[J]. 中国表面工程, 2021, 34(3): 1-15.
YI H, HUANG R F, CAO H J, et al.Research Progress and Prospects of CMT-Based Wire Arc Additive Manufacturing Technology for Titanium Alloys[J]. China Surface Engineering, 2021, 34(3): 1-15.
[2] DING J, COLEGROVE P, MEHNEN J, et al.Thermo-Mechanical Analysis of Wire and Arc Additive Layer Manufacturing Process on Large Multi-Layer Parts[J]. Computational Materials Science, 2011, 50(12): 3315-3322.
[3] DICKENS P M, PRIDHAM M S, COBB R C, et al.Rapid Prototyping Using 3-D Welding[C]//1992 International Solid Freeform Fabrication Symposium, 1992.
[4] SPENCER J D, DICKENS P M, WYKES C M.Rapid Prototyping of Metal Parts by Three-Dimensional Welding[J]. Proceedings of the Institution of Mechanical Engineers, Part B: Journal of Engineering Manufacture, 1998, 212(3): 175-182.
[5] GUNGOR B, KALUC E, TABAN E, et al.Mechanical and Microstructural Properties of Robotic Cold Metal Transfer (CMT) Welded 5083-H111 and 6082-T651 Aluminum Alloys[J]. Materials & Design (1980-2015), 2014, 54: 207-211.
[6] 侯旭儒, 赵琳, 任淑彬, 等. 热输入对电弧增材制造船用高强钢组织与力学性能的影响[J]. 金属学报, 2023, 59(10): 1311-1323.
HOU X R, ZHAO L, REN S B, et al.Effect of Heat Input on Microstructure and Mechanical Properties of Marine High Strength Steel Fabricated by Wire Arc Additive Manufacturing[J]. Acta Metallurgica Sinica, 2023, 59(10): 1311-1323.
[7] YANG J W, YI H, JIA L, et al.Particle Sedimentation in Cored-Wire-Arc Directed Energy Deposition: Particle Migration and Suppression Mechanism via Ultrasonic Vibration[J]. International Journal of Heat and Mass Transfer, 2025, 237: 126446.
[8] 韩文涛, 林健, 雷永平, 等. 不同层间停留时间下电弧增材制造2Cr13薄壁件热力学行为[J]. 焊接学报, 2019, 40(12): 47-52.
HAN W T, LIN J, LEI Y P, et al.Thermal-Stress Analysis of Wire-Arc Additive Manufacturing 2Cr13 Parts with Different Interlayer Idle Time[J]. Transactions of the China Welding Institution, 2019, 40(12): 47-52.
[9] 林筱鹏. CMT电弧增材制造Inconel625合金枝晶动态演化过程多尺度模拟研究[D]. 镇江: 江苏科技大学, 2023.
LIN X P.Multi-scale Simulation Study on the Dynamic Evolution of Inconel 625 Alloy Dendrites by CMT Arc Additive Manufacturing[D]. Zhenjiang: Jiangsu University of Science and Technology, 2023.
[10] 郭龙龙, 徐斌荣, 刘春伟, 等. 基于CMT的30CrMo增材再制造工艺及力学性能[J]. 兵器材料科学与工程, 2023, 46(2): 29-36.
GUO L L, XU B R, LIU C W, et al.Additive Remanufacturing Process and Mechanical Properties of 30CrMo Basedon CMT[J]. Ordnance Material Science and Engineering, 2023, 46(2): 29-36.
[11] ABERBACHE H, MATHIEU A, HAGLON N, et al.Numerical Study of the Cold Metal Transfer (CMT) Welding of Thin Austenitic Steel Plates with an Equivalent Heat Source Approach[J]. Journal of Manufacturing and Materials Processing, 2024, 8(1): 20.
[12] WILSON-HEID A E, WANG Z Q, MCCORNAC B, et al. Quantitative Relationship between Anisotropic Strain to Failure and Grain Morphology in Additively Manufactured Ti-6Al-4V[J]. Materials Science and Engineering: A, 2017, 706: 287-294.
[13] MENG W, CHEN K, PAN Q Y, et al.Narrow Gap Welding of 316L Thick-Section Steel with Cold Metal Transition Pulsed Arc Swing[J]. The International Journal of Advanced Manufacturing Technology, 2024, 132(7): 4035-4053.
[14] 蔚慧忠. 电弧增材制造17-4PH不锈钢工艺、组织与性能研究[D]. 天津: 天津理工大学, 2023.
YU H Z.Study on Process Microstructure Andproperties of 17-4PH Stainless Steel by Wire Wire Arc Additive Manufacturing[D]. Tianjin: Tianjin University of Technology, 2023.
[15] 刘爱军, 王国平, 钟志宏, 等. CMT堆焊低合金钢的组织和性能及其冲击断裂行为[J]. 焊接, 2020(4): 11-15.
LIU A J, WANG G P, ZHONG Z H, et al.Microstructure, properties and Impact Fracture Behavior of CMT Surfacing Low Alloy Steel[J]. Welding & Joining, 2020(4): 11-15.
[16] 陈玉喜, 张文浩, 孟威. 冷金属过渡丝弧成形奥氏体不锈钢工艺特征研究[J]. 焊接技术, 2020, 49(3): 26-29.
CHEN Y X, ZHANG W H, MENG W.Study on Process Characteristics of Cold Metal Transition Wire Arc Forming Austenitic Stainless Steel[J]. Welding Technology, 2020, 49(3): 26-29.
[17] 吕飞阅, 王磊磊, 高转妮, 等. CMT电弧增材制造过程电弧特性对熔滴过渡行为的影响机理研究[J]. 机械工程学报, 2023, 59(15): 267-281.
LYU F Y, WANG L L, GAO Z N, et al.Influence Mechanism of Arc Characteristics on Droplet Transfer Behavior in CMT-Based Additive Manufacturing[J]. Journal of Mechanical Engineering, 2023, 59(15): 267-281.
[18] GE J G, LIN J, LEI Y P, et al.Location-Related Thermal History, Microstructure, and Mechanical Properties of Arc Additively Manufactured 2Cr13 Steel Using Cold Metal Transfer Welding[J]. Materials Science and Engineering: A, 2018, 715: 144-153.
[19] 李敬勇, 李超然, 徐育烺, 等. 层间温度对CMT电弧增材制造2Cr13不锈钢薄壁件成形及组织和性能影响[J]. 焊接, 2024(2): 43-50.
LI J Y, LI C R, XU Y L, et al.Effect of Interlayer Temperature on the Forming, Microstructure and Mechanical Properties of 2Cr13 Stainless Steel Thin-Walled Parts by CMT Arc Additive Manufacturing[J]. Welding & Joining, 2024(2): 43-50.
[20] 李超然. 机器人CMT电弧增材制造马氏体不锈钢多层结构试验研究[D]. 镇江: 江苏科技大学, 2022.
LI C R.Experimental Research on Multi-layer Structure of Martensitic Stainless Steel by Robotic CMT Arc Additive Manufacturing[D]. Zhenjiang: Jiangsu University of Science and Technology, 2022.
[21] 郭亿, 王金凤, 苏文超, 等. 电弧熔覆韧-硬复合层工艺及性能研究[J]. 精密成形工程, 2024, 16(6): 107-114.
GUO Y, WANG J F, SU W C, et al.Process and Properties of Arc Cladding Ductile-Hard Composite Layer[J]. Journal of Netshape Forming Engineering, 2024, 16(6): 107-114.
[22] 王金凤, 井子润, 杨伟, 等. 激光熔覆与等离子熔覆的镍基合金熔覆层组织和性能对比[J]. 材料保护, 2020, 53(1): 80-83.
WANG J F, JING Z R, YANG W, et al.Effect of Laser Cladding and Plasma Cladding on Microstructure and Properties of Nickel-Based Alloy Cladding Layer[J]. Materials Protection, 2020, 53(1): 80-83.
[23] 毛展召, 余圣甫. 5CrNiMo钢表面电弧增材制造梯度结构用药芯丝材的研制及应用[J]. 机械工程材料, 2020, 44(4): 46-51.
MAO Z Z, YU S F.Development and Application of Wire and Arc Additive Manufacturing Flux Cored Wire for Gradient Structure on Surface of 5CrNiMo Steel[J]. Materials for Mechanical Engineering, 2020, 44(4): 46-51.
[24] 马笑晗, 贺定勇, 秦志恒, 等. TiC对亚共晶高铬铸铁堆焊合金组织及磨损性能的影响[J]. 中国表面工程, 2024, 37(4): 142-150.
MA X H, HE D Y, QIN Z H, et al.Effects of TiC on the Microstructure and Wear Resistance of Hypoeutectic Fe-Cr-C Hardfacing Alloy[J]. China Surface Engineering, 2024, 37(4): 142-150.
[25] 唐然. H13钢非平衡凝固组织与性能研究[D]. 大连: 大连交通大学, 2023.
TANG R.Investigation on the Microstructure and Properties of Non-equilibrium Solidification H13 Steel[D]. Dalian: Dalian Jiaotong University, 2023.
[26] 耿伟, 朱志宝, 马金辉, 等. 9Cr-2W-3Co马氏体耐热钢高温力学性能与断裂机理[J]. 特殊钢, 2025, 46(3): 45-51.
GENG W, ZHU Z B, MA J H, et al.High Temperature Mechanical Properties and Fracture Mechanism of 9Cr-2W-3Co Martensitic Heat-Resistant Steel[J]. Special Steel, 2025, 46(3): 45-51.
[27] 樊译. 4Cr13型耐蚀塑料模具钢组织均匀性调控与腐蚀磨损机理研究[D]. 北京: 钢铁研究总院, 2024: 136-139.
FAN Y.Study on Microstructure Uniformity Control and Corrosion Wear Mechanism of 4Cr13 Corrosion Resistant Plastic Die Steel[D]. Beijing: Central Iron and Steel Research Institute, 2024: 136-139.
[28] 杨宝震. 碳化物强化Fe-Cr-Ni系中熵合金的组织及性能研究[D]. 长沙: 中南大学, 2022.
YANG B Z.Microstructures and Properties of Carbides Reinforced Fe-Cr-Ni Series Medium-Entropy Alloys[D]. Changsha: Central South University, 2022.
基金
湖北省自然科学基金联合基金(202AFD184); 湖北优秀中青年科学技术创新团队(T2024015); 湖北汽车工业学院揭榜挂帅项目(2024JBA04); 大学生创新创业训练计划项目(DC2022051)