基于原子制造的非晶新材料探索

童星, 闫玉强, 柯海波, 汪卫华

精密成形工程 ›› 2025, Vol. 17 ›› Issue (12) : 1-14.

PDF(27847 KB)
PDF(27847 KB)
精密成形工程 ›› 2025, Vol. 17 ›› Issue (12) : 1-14. DOI: 10.3969/j.issn.1674-6457.2025.12.001
高熵与非晶合金的先进成型工程

基于原子制造的非晶新材料探索

  • 童星1, 闫玉强1, 柯海波1,*, 汪卫华1,2,*
作者信息 +

Exploration of New Amorphous Materials via Atomic Manufacturing

  • TONG Xing1, YAN Yuqiang1, KE Haibo1,*, WANG Weihua1,2,*
Author information +
文章历史 +

摘要

非晶材料在人类文明与科学发展中具有重要地位,而非晶合金作为新型非晶态材料,因长程无序、短程有序的原子结构展现出高强度、高硬度等优异性能,在多个领域具有广阔的应用前景。然而,传统自上而下的快速冷却制备工艺受限于高冷却速率依赖、成分敏感性高、结构均匀性差等问题。近年来,自下而上的原子制造理念为非晶合金制备提供了新思路。原子制造以原子或原子团簇为基本构筑单元,通过可控生成、沉积与拼接实现宏观材料构筑,可绕过熔体冷却路径的限制,突破传统工艺瓶颈。本文综述了原子制造在非晶材料领域的代表性研究进展,包括超稳定玻璃的制备、单质金属玻璃化、结构与性能的多样化调控以及高熵无序合金的精准组装。同时也指出原子制造仍面临团簇源可控生成难、界面连接机理不明、跨尺度性能映射缺失等技术挑战。未来,基于原子制造的非晶材料研究有望推动新型非晶材料探索,深化对非晶形成机制与非晶结构的理解,通过突破性能极限,促进非晶合金在高性能结构件、功能器件及能源转换领域的广泛应用。

Abstract

Amorphous materials play a significant role in development of human civilization and science. Among them, amorphous alloys, as a novel class of amorphous materials, exhibit superior properties such as high strength and high hardness due to their atomic structure characterized by long-range disorder and short-range order, offering broad application prospects across various fields. However, conventional top-down rapid quenching techniques are constrained by their reliance on extremely high cooling rates, high compositional sensitivity, and poor structural uniformity. In recent years, the bottom-up concept of atomic manufacturing has provided a new pathway for the preparation of amorphous alloys. With atoms or atomic clusters as the fundamental building blocks, atomic manufacturing enables the construction of bulk materials through controllable generation, deposition, and assembly, thereby bypassing the limitations of melt-quenching routes and overcoming bottlenecks in traditional processing. The representative advances of atomic manufacturing in the field of amorphous materials are summarized, including the preparation of ultrastable glasses, vitrification of monatomic metal, structural and property diversification, and the precise assembly of high-entropy disordered alloys. Nevertheless, there exist some challenges, such as the controlled generation of cluster sources, unclear interfacial bonding mechanisms, and the lack of cross-scale property mapping. Atomic manufacturing is expected to drive the exploration of novel amorphous materials, deepen the understanding of glass formation mechanisms and structural fundamentals, and promote the broad application of amorphous alloys in high-performance structural components, functional devices, and energy conversion systems.

关键词

原子制造 / 非晶材料 / 原子团簇 / 多尺度组装 / 材料性能调控

Key words

atomic manufacturing / amorphous materials / atomic clusters / multi-scale assembly / material properties controlling

引用本文

导出引用
童星, 闫玉强, 柯海波, 汪卫华. 基于原子制造的非晶新材料探索[J]. 精密成形工程. 2025, 17(12): 1-14 https://doi.org/10.3969/j.issn.1674-6457.2025.12.001
TONG Xing, YAN Yuqiang, KE Haibo, WANG Weihua. Exploration of New Amorphous Materials via Atomic Manufacturing[J]. Journal of Netshape Forming Engineering. 2025, 17(12): 1-14 https://doi.org/10.3969/j.issn.1674-6457.2025.12.001
中图分类号: TG139.8   

参考文献

[1] 汪卫华. 非晶态物质的本质和特性[J]. 物理学进展, 2013, 33(5): 177-351.
WANG W H.The Nature and Properties of Amorphous Matter[J]. Progress in Physics, 2013, 33(5): 177-351.
[2] 汪卫华. 非晶物质——常规物质第四态(第一卷)[M]. 北京: 科学出版社, 2023.
WANG W H.Amorphous Matter-the Fourth State of Conventional Matter (Volume 1)[M]. Beijing: Science Press, 2023.
[3] 柯海波, 周靖, 童星, 等. 非晶物质的前沿发展现状与未来展望[J]. 科技导报, 2025, 43(15): 20-38.
KE H B, ZHOU J, TONG X, et al.Current Status and Future Prospects of Cutting-Edge Development of Amorphous Materials[J]. Science & Technology Review, 2025, 43(15): 20-38.
[4] JOHNSON W L.Bulk Amorphous Metal—An Emerging Engineering Material[J]. JOM, 2002, 54(3): 40-43.
[5] KAKIUCHI H, INOUE A, ONUKI M, et al.Application of Zr-Based Bulk Glassy Alloys to Golf Clubs[J]. Materials Transactions, 2001, 42(4): 678-681.
[6] HAMILL L, ROBERTS S, DAVIDSON M, et al.Hypervelocity Impact Phenomenon in Bulk Metallic Glasses and Composites[J]. Advanced Engineering Materials, 2014, 16(1): 85-93.
[7] HOFMANN D C, ANDERSEN L M, KOLODZIEJSKA J, et al.Optimizing Bulk Metallic Glasses for Robust, Highly Wear-Resistant Gears[J]. Advanced Engineering Materials, 2017, 19(1): 1600541.
[8] HOFMANN D C, SUH J Y, WIEST A, et al.Designing Metallic Glass Matrix Composites with High Toughness and Tensile Ductility[J]. Nature, 2008, 451(7182): 1085-1089.
[9] YOSHIZAWA Y, OGUMA S, YAMAUCHI K.New Fe-Based Soft Magnetic Alloys Composed of Ultrafine Grain Structure[J]. Journal of Applied Physics, 1988, 64(10): 6044-6046.
[10] SILVEYRA J M, FERRARA E, HUBER D L, et al. Soft Magnetic Materials for a Sustainable and Electrified World[J]. Science, 2018, 362(6413): eaao0195.
[11] TAKENAKA K, SETYAWAN A D, ZHANG Y, et al.Production of Nanocrystalline (Fe, Co)-Si-B-P-Cu Alloy with Excellent Soft Magnetic Properties for Commercial Applications[J]. Materials Transactions, 2015, 56(3): 372-376.
[12] LUBORSKY F E, BECKER J J, FRISCHMANN P G, et al.Potential of Amorphous Alloys for Application in Magnetic Devices[J]. Journal of Applied Physics, 1978, 49(3): 1769-1774.
[13] INOUE A, KONG F L, HAN Y, et al.Development and Application of Fe-Based Soft Magnetic Bulk Metallic Glassy Inductors[J]. Journal of Alloys and Compounds, 2018, 731: 1303-1309.
[14] XIE G Q, QIN F X, ZHU S L.Recent Progress in Ti-Based Metallic Glasses for Application as Biomaterials[J]. Materials Transactions, 2013, 54(8): 1314-1323.
[15] CALIN M, GEBERT A, GHINEA A C, et al.Designing Biocompatible Ti-Based Metallic Glasses for Implant Applications[J]. Materials Science and Engineering: C, 2013, 33(2): 875-883.
[16] GONG P, DENG L, JIN J S, et al.Review on the Research and Development of Ti-Based Bulk Metallic Glasses[J]. Metals, 2016, 6(11): 264.
[17] XIE G Q, KANETAKA H, KATO H, et al.Porous Ti-Based Bulk Metallic Glass with Excellent Mechanical Properties and Good Biocompatibility[J]. Intermetallics, 2019, 105: 153-162.
[18] SUN K, FU R, LIU X W, et al.Osteogenesis and Angiogenesis of a Bulk Metallic Glass for Biomedical Implants[J]. Bioactive Materials, 2022, 8: 253-266.
[19] YAN W, RICHARD I, KURTULDU G, et al.Structured Nanoscale Metallic Glass Fibres with Extreme Aspect Ratios[J]. Nature Nanotechnology, 2020, 15(10): 875-882.
[20] LIU Y H, LIU J B, SOHN S, et al.Metallic Glass Nanostructures of Tunable Shape and Composition[J]. Nature Communications, 2015, 6: 7043.
[21] CHU J P, JANG J S C, HUANG J C, et al. Thin Film Metallic Glasses: Unique Properties and Potential Applications[J]. Thin Solid Films, 2012, 520(16): 5097-5122.
[22] LI H X, LU Z C, WANG S L, et al.Fe-Based Bulk Metallic Glasses: Glass Formation, Fabrication, Properties and Applications[J]. Progress in Materials Science, 2019, 103: 235-318.
[23] ZHAO H W, CHEN X J, WANG G Z, et al.Two-Dimensional Amorphous Nanomaterials: Synthesis and Applications[J]. 2D Materials, 2019, 6(3): 032002.
[24] HAN D X, WANG G, REN J L, et al.Stick-Slip Dynamics in a Ni62Nb38 Metallic Glass Film during Nanoscratching[J]. Acta Materialia, 2017, 136: 49-60.
[25] KRAMER J.Der Amorphe Zustand Der Metalle[J]. Zeitschrift Für Physik, 1937, 106(11): 675-691.
[26] KLEMENT W, WILLENS R H, DUWEZ P.Non-Crystalline Structure in Solidified Gold-Silicon Alloys[J]. Nature, 1960, 187(4740): 869-870.
[27] SCHRÖDER H, SAMWER K, KÖSTER U. Micromechanism for Metallic-Glass Formation by Solid-State Reactions[J]. Physical Review Letters, 1985, 54(3): 197-200.
[28] INOUE A.Bulk Amorphous Alloys with Soft and Hard Magnetic Properties[J]. Materials Science and Engineering: A, 1997, 226: 357-363.
[29] JOHNSON W L.Bulk Glass-Forming Metallic Alloys: Science and Technology[J]. MRS Bulletin, 1999, 24(10): 42-56.
[30] KUMAR G, TANG H X, SCHROERS J.Nanomoulding with Amorphous Metals[J]. Nature, 2009, 457(7231): 868-872.
[31] ZHANG C, WANG W, LI Y C, et al.3D Printing of Fe-Based Bulk Metallic Glasses and Composites with Large Dimensions and Enhanced Toughness by Thermal Spraying[J]. Journal of Materials Chemistry A, 2018, 6(16): 6800-6805.
[32] LI M X, ZHAO S F, LU Z, et al.High-Temperature Bulk Metallic Glasses Developed by Combinatorial Methods[J]. Nature, 2019, 569(7754): 99-103.
[33] MA J, YANG C, LIU X D, et al. Fast Surface Dynamics Enabled Cold Joining of Metallic Glasses[J]. Science Advances, 2019, 5(11): eaax7256.
[34] SOHRABI S, FU J N, LI L Y, et al.Manufacturing of Metallic Glass Components: Processes, Structures and Properties[J]. Progress in Materials Science, 2024, 144: 101283.
[35] 那慧康, 杨九卿, 寇生中, 等. 非晶合金的铸造工艺研究进展[J]. 精密成形工程, 2024, 16(12): 218-230.
NA H K, YANG J Q, KOU S Z, et al.Research Progress of Amorphous Alloy Casting Process[J]. Journal of Netshape Forming Engineering, 2024, 16(12): 218-230.
[36] LI M X, SUN Y T, WANG C, et al.Data-Driven Discovery of a Universal Indicator for Metallic Glass Forming Ability[J]. Nature Materials, 2021, 21(2): 165-172.
[37] LI Y, GUO Q, KALB J A, et al.Matching Glass-Forming Ability with the Density of the Amorphous Phase[J]. Science, 2008, 322(5909): 1816-1819.
[38] TONG X, WANG G, YI J, et al.Shear Avalanches in Plastic Deformation of a Metallic Glass Composite[J]. International Journal of Plasticity, 2016, 77: 141-155.
[39] ŞOPU D, STUKOWSKI A, STOICA M, et al.Atomic-Level Processes of Shear Band Nucleation in Metallic Glasses[J]. Physical Review Letters, 2017, 119(19): 195503.
[40] QIAO J C, WANG Q, PELLETIER J M, et al.Structural Heterogeneities and Mechanical Behavior of Amorphous Alloys[J]. Progress in Materials Science, 2019, 104: 250-329.
[41] WAGNER H, BEDORF D, KÜCHEMANN S, et al. Local Elastic Properties of a Metallic Glass[J]. Nature Materials, 2011, 10(6): 439-442.
[42] ICHITSUBO T, MATSUBARA E, YAMAMOTO T, et al.Microstructure of Fragile Metallic Glasses Inferred from Ultrasound-Accelerated Crystallization in Pd-Based Metallic Glasses[J]. Physical Review Letters, 2005, 95(24): 245501.
[43] DEBENEDETTI P G, STILLINGER F H.Supercooled Liquids and the Glass Transition[J]. Nature, 2001, 410(6825): 259-267.
[44] PAULY S, LÖBER L, PETTERS R, et al. Processing Metallic Glasses by Selective Laser Melting[J]. Materials Today, 2013, 16(1/2): 37-41.
[45] 宋凤麒, 戴庆. 原子制造:物质科学的未来技术[J]. 物理, 2023, 52(6): 371-380.
SONG F Q, DAI Q.Atom Manufacturing: A Future Technique of Physical Sciences[J]. Physics, 2023, 52(6): 371-380.
[46] 雒建斌, 郭东明, 杨华勇, 等. 原子级制造的关键基础科学问题[J]. 中国科学基金, 2024, 38(1): 86-98.
LUO J B, GUO D M, YANG H Y, et al.Key Basic Scientific Issues in Atomic Level Manufacturing[J]. Bulletin of National Natural Science Foundation of China, 2024, 38(1): 86-98.
[47] CHEN R T, REN Z F, LIANG Y, et al.Spatiotemporal Imaging of Charge Transfer in Photocatalyst Particles[J]. Nature, 2022, 610(7931): 296-301.
[48] MO M Z, CHEN Z, LI R K, et al.Heterogeneous to Homogeneous Melting Transition Visualized with Ultrafast Electron Diffraction[J]. Science, 2018, 360(6396): 1451-1455.
[49] SHENG H W, LUO W K, ALAMGIR F M, et al.Atomic Packing and Short-to-Medium-Range Order in Metallic Glasses[J]. Nature, 2006, 439(7075): 419-425.
[50] MIRACLE D B.A Structural Model for Metallic Glasses[J]. Nature Materials, 2004, 3(10): 697-702.
[51] WU Z W, LI M Z, WANG W H, et al.Hidden Topological Order and Its Correlation with Glass-Forming Ability in Metallic Glasses[J]. Nature Communications, 2015, 6: 6035.
[52] SHIH C Y, CHEN C B, REHBOCK C, et al.Limited Elemental Mixing in Nanoparticles Generated by Ultrashort Pulse Laser Ablation of AgCu Bilayer Thin Films in a Liquid Environment: Atomistic Modeling and Experiments[J]. The Journal of Physical Chemistry C, 2021, 125(3): 2132-2155.
[53] TONG X, ZHANG Y, WANG Y C, et al.Structural Origin of Magnetic Softening in a Fe-Based Amorphous Alloy Upon Annealing[J]. Journal of Materials Science & Technology, 2022, 96: 233-240.
[54] ZHANG Z D, YE S M, UMETSU R, et al.Pulse Current Training Induced Marked Improvement of Soft Magnetic Properties in Fe-Based Amorphous Alloys[J]. Materials Research Letters, 2025, 13(2): 148-154.
[55] SHANG B S, WANG W H, GUAN P F.Cycle Deformation Enabled Controllable Mechanical Polarity of Bulk Metallic Glasses[J]. Acta Materialia, 2022, 225: 117557.
[56] DI LISIO V, GALLINO I, RIEGLER S S, et al.Size-Dependent Vitrification in Metallic Glasses[J]. Nature Communications, 2023, 14: 4698.
[57] TIAN H K, XU Q Y, ZHANG H Y, et al.Surface Dynamics of Glasses[J]. Applied Physics Reviews, 2022, 9: 011316.
[58] NAKAMURO T, SAKAKIBARA M, NADA H, et al.Capturing the Moment of Emergence of Crystal Nucleus from Disorder[J]. Journal of the American Chemical Society, 2021, 143(4): 1763-1767.
[59] CAO C R, HUANG K Q, SHI J A, et al.Liquid-Like Behaviours of Metallic Glassy Nanoparticles at Room Temperature[J]. Nature Communications, 2019, 10: 1966.
[60] WANG Z, WANG W H.Flow Units as Dynamic Defects in Metallic Glassy Materials Open Access[J]. National Science Review, 2019, 6(2): 304-323.
[61] YU H B, TYLINSKI M, GUISEPPI-ELIE A, et al.Suppression of β Relaxation in Vapor-Deposited Ultrastable Glasses[J]. Physical Review Letters, 2015, 115(18): 185501.
[62] LU Z, JIAO W, WANG W H, et al.Flow Unit Perspective on Room Temperature Homogeneous Plastic Deformation in Metallic Glasses[J]. Physical Review Letters, 2014, 113(4): 045501.
[63] TANG X C, NGUYEN T, YAO X H, et al.A Cavitation and Dynamic Void Growth Model for a General Class of Strain-Softening Amorphous Materials[J]. Journal of the Mechanics and Physics of Solids, 2020, 141: 104023.
[64] LI L, HU L N, ZHANG L Y, et al.Ultra-Stable Metallic Glass Generated by Modulation of Melt State[J]. Rare Metals, 2025, 44(3): 1917-1931.
[65] DAMASCENO P F, ENGEL M, GLOTZER S C.Predictive Self-Assembly of Polyhedra into Complex Structures[J]. Science, 2012, 337(6093): 453-457.
[66] WANG W, ZHAO R, HAN R, et al.Metallic Glass Roadmap[J]. Materials Futures, 2025, 4: 033001.
[67] KETOV S V, SUN Y H, NACHUM S, et al.Rejuvenation of Metallic Glasses by Non-Affine Thermal Strain[J]. Nature, 2015, 524(7564): 200-203.
[68] SUN Y T, ZHAO R, DING D W, et al.Distinct Relaxation Mechanism at Room Temperature in Metallic Glass[J]. Nature Communications, 2023, 14: 540.
[69] WANG W H.Dynamic Relaxations and Relaxation-Property Relationships in Metallic Glasses[J]. Progress in Materials Science, 2019, 106: 100561.
[70] YU H B, WANG W H, BAI H Y, et al.Relating Activation of Shear Transformation Zones to β Relaxations in Metallic Glasses[J]. Physical Review B, 2010, 81(22): 220201.
[71] WANG J Q, SHEN Y, PEREPEZKO J H, et al.Increasing the Kinetic Stability of Bulk Metallic Glasses[J]. Acta Materialia, 2016, 104: 25-32.
[72] ZHAO Y, SHANG B S, ZHANG B, et al. Ultrastable Metallic Glass by Room Temperature Aging[J]. Science Advances, 2022, 8(33): eabn3623.
[73] GAO L, YU H B, SCHRØDER T B, et al. Unified Percolation Scenario for the α and β Processes in Simple Glass Formers[J]. Nature Physics, 2025, 21(3): 471-479.
[74] TONG X, WANG G, STACHURSKI Z H, et al.Structural Evolution and Strength Change of a Metallic Glass at Different Temperatures[J]. Scientific Reports, 2016, 6: 30876.
[75] SWALLEN S F, KEARNS K L, MAPES M K, et al.Organic Glasses with Exceptional Thermodynamic and Kinetic Stability[J]. Science, 2007, 315(5810): 353-356.
[76] YU H B, LUO Y S, SAMWER K.Ultrastable Metallic Glass[J]. Advanced Materials, 2020, 25: 5904-5908.
[77] AJI D P B, HIRATA A, ZHU F. Ultrastrong and Ultrastable Metallic Glass[J]. ArXiv Preprint, 2013, 1306: 1575.
[78] LUO P, CAO C R, ZHU F, et al.Ultrastable Metallic Glasses Formed on Cold Substrates[J]. Nature Communications, 2018, 9: 1389.
[79] LUO P, WOLF S E, GOVIND S, et al.High-Density Stable Glasses Formed on Soft Substrates[J]. Nature Materials, 2024, 23(5): 688-694.
[80] BERTHIER L, EDIGER M D.Facets of Glass Physics[J]. Physics Today, 2016, 69(1): 40-46.
[81] ROTH C B.Forming Denser Glasses on Soft Substrates[J]. Nature Materials, 2024, 23(5): 587-588.
[82] KAUZMANN W.The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures[J]. Chemical Reviews, 1948, 43(2): 219-256.
[83] ZHONG L, WANG J W, SHENG H W, et al.Formation of Monatomic Metallic Glasses through Ultrafast Liquid Quenching[J]. Nature, 2014, 512(7513): 177-180.
[84] TONG X, ZHANG Y E, SHANG B S, et al.Breaking the Vitrification Limitation of Monatomic Metals[J]. Nature Materials, 2024, 23(9): 1193-1199.
[85] BAI H-Y, TONG X.A General Strategy for the Vitrification of Monatomic Metals[J]. Nature Materials, 2024, 23(9): 1165-1166.
[86] GHIDELLI M, OREKHOV A, BASSI A L, et al.Novel Class of Nanostructured Metallic Glass Films with Superior and Tunable Mechanical Properties[J]. Acta Materialia, 2021, 213: 116955.
[87] ZHAO H, ZHOU J, LIU X, et al.High-Strength and Malleable Dual-Phase Nanostructured Ta-Based Metallic Glass via Atomic Manufacturing[J]. Science China Materials, 2023, 66(11): 4226-4232.
[88] SHAO L L, BAI R S, WU Y X, et al.Critical State-Induced Emergence of Superior Magnetic Performances in an Iron-Based Amorphous Soft Magnetic Composite[J]. Materials Futures, 2024, 3(2): 025301.
[89] LIU Y W, LIU C, CHEN Z L, et al.Fabrication of Amorphous PdNiCuP Nanoparticles as Efficient Bifunctional and Highly Durable Electrocatalyst for Methanol and Formic Acid Oxidation[J]. Journal of Materials Science & Technology, 2022, 122: 148-155.
[90] LI Z M, PRADEEP K G, DENG Y, et al.Metastable High-Entropy Dual-Phase Alloys Overcome the Strength-Ductility Trade-off[J]. Nature, 2016, 534(7606): 227-230.
[91] LEI Z F, LIU X J, WU Y, et al.Enhanced Strength and Ductility in a High-Entropy Alloy via Ordered Oxygen Complexes[J]. Nature, 2018, 563(7732): 546-550.
[92] GLUDOVATZ B, HOHENWARTER A, CATOOR D, et al.A Fracture-Resistant High-Entropy Alloy for Cryogenic Applications[J]. Science, 2014, 345(6201): 1153-1158.
[93] YAO Y G, DONG Q, BROZENA A, et al. High-Entropy Nanoparticles: Synthesis-Structure-Property Relationships and Data-Driven Discovery[J]. Science, 2022, 376(6589): eabn3103.
[94] WANG W H.High-Entropy Metallic Glasses[J]. Jom, 2014, 66(10): 2067-2077.
[95] CAO G H, LIANG J J, GUO Z L, et al.Liquid Metal for High-Entropy Alloy Nanoparticles Synthesis[J]. Nature, 2023, 619(7968): 73-77.
[96] LIANG S X, JIA Z, LIU Y J, et al.Compelling Rejuvenated Catalytic Performance in Metallic Glasses[J]. Advanced Materials, 2018, 30(45): 1802764.
[97] WANG X F, PAWAR G, LI Y J, et al.Glassy Li Metal Anode for High-Performance Rechargeable Li Batteries[J]. Nature Materials, 2020, 19(12): 1339-1345.
[98] SALINGA M, KERSTING B, RONNEBERGER I, et al.Monatomic Phase Change Memory[J]. Nature Materials, 2018, 17(8): 681-685.
[99] LAN S, ZHU L, WU Z D, et al.A Medium-Range Structure Motif Linking Amorphous and Crystalline States[J]. Nature Materials, 2021, 20(10): 1347-1352.
[100] ZHANG Y, LI Z Z, TONG X, et al.Three-Dimensional Atomic Insights into the Metal-Oxide Interface in Zr-ZrO2 Nanoparticles[J]. Nature Communications, 2024, 15: 7624.

基金

国家自然科学基金(52471180); 广东省基础与应用基础研究基金(2024A1515140156,2019B030302010); 广东省量子科学战略专项(GDZX2301001); 广东省人才项目(2024TQ08C641); 松湖青年学者计划

PDF(27847 KB)

Accesses

Citation

Detail

段落导航
相关文章

/