目的 以短切碳纤维增强尼龙6复合材料(CF/PA6)为研究对象,系统探究了预浸料片材长宽比对其力学性能的影响规律,进而提出了一种短切预浸料片材的尺度优选方法。方法 制备了4种长宽比(1∶1、2∶1、4∶1、6∶1)的短切CF/PA6预浸料片材,通过排气辅助模压成型工艺制备出力学性能测试样件,利用光学显微镜与显微CT定量表征微观孔隙与纤维面外波纹缺陷,并结合拉伸实验分析片材尺度对宏观力学性能的影响。结果 随片材长宽比的增大,材料内部孔隙分布均匀性下降,大尺寸(≥1015 nm3)孔隙数量增多,同时纤维面外波纹显著加剧,平均波纹比与波纹角分别提高了122%与140%。拉伸性能与模量均随着长宽比的增大呈现先升后降的趋势,并于2∶1时达到最优值。结论 短切预浸料片材长宽比通过影响微观缺陷的演化与应力传递结构的连续性来影响复合材料力学性能。当长宽比为2∶1时,可实现纤维应力传递效率与缺陷抑制的有效平衡,为其在复杂结构件中的性能优化与工艺设计提供了重要依据。
Abstract
The work aims to investigate chopped carbon fiber reinforced polyamide 6 (CF/PA6) composites to systematically examine the effect of sheet aspect ratio on mechanical properties, so as to propose an optimal selection methodology for prepreg sheet dimensions. Four types of CF/PA6 sheets with aspect ratios of 1∶1, 2∶1, 4∶1, and 6∶1 were prepared. Test specimens were fabricated through an exhaust-assisted compression molding process. Microstructural defects such as pores and out-of-plane fiber waviness were quantitatively characterized with optical microscopy and micro-CT, while tensile tests were conducted to evaluate macro-mechanical properties. With the increasing aspect ratio, the uniformity of pore distribution decreased, and the number of large pores (≥1015 nm3) increased. Meanwhile, out-of-plane fiber waviness became more severe, with the average waviness ratio and waviness angle increasing by 122% and 140%, respectively. Both tensile strength and modulus initially increased and then decreased as the aspect ratio increased, peaking at an aspect ratio of 2∶1. The aspect ratio of chopped prepreg sheets affects the mechanical properties of composites by influencing the evolution of microscopic defects and the continuity of stress transfer pathways. An aspect ratio of 2∶1 achieves an optimal balance between efficient stress transmission and defect suppression, providing critical insight for performance optimization and process design of complex structural components.
关键词
短切预浸料片材 /
模压成型 /
CF/PA6复合材料 /
微观缺陷 /
力学性能
Key words
chopped prepreg sheets /
compression molding /
CF/PA6 composites /
microstructural defects /
mechanical properties
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参考文献
[1] 李含宇. 树脂基碳纤维复合材料负重轮模压成型工艺研究[D]. 哈尔滨: 哈尔滨工业大学, 2022: 3-7.
LI H Y.Research on Molding Technology of Resin Based Carbon Fiber Composite Roadwheel[D]. Harbin: Harbin Institute of Technology, 2022: 3-7.
[2] 梁春祖, 罗锦涛, 刘强, 等. 碳纤维/环氧复合材料大开口支架结构固化变形仿真模拟[J]. 精密成形工程, 2025, 17(9): 212-221.
LIANG C Z, LUO J T, LIU Q, et al.Finite-Element Investigation into Curing-Induced Deformations of Carbon/Epoxy Composite Large-Opening Support Structures[J]. Journal of Netshape Forming Engineering, 2025, 17(9): 212-221.
[3] 曹建凡, 白树林, 秦文贞, 等. 碳纤维增强热塑性复合材料的制备与性能研究进展[J]. 复合材料学报, 2023, 40(3): 1229-1247.
CAO J F, BAI S L, QIN W Z, et al.Research Progress on Preparation and Properties of Carbon Fiber Reinforced Thermoplastic Composites[J]. Acta Materiae Compositae Sinica, 2023, 40(3): 1229-1247.
[4] WANG H, HUO S Q, CHEVALI V, et al.Carbon Fiber Reinforced Thermoplastics: From Materials to Manufacturing and Applications[J]. Advanced Materials, 2025, 37(27): 2418709.
[5] 王晓雨. 碳纤维增强尼龙6自阻加热模压成型工艺及性能研究[D]. 长沙: 中南大学, 2022: 1-7.
WANG X Y.Research on the Process and Properties of Carbon Fiber Reinforced Nylon 6 Composites Formed by Compression Molding Process with Self-resistance Electric Heating Technology[D]. Changsha: Central South University, 2022: 1-7.
[6] ALMUSHAIKEH A M, ALASWAD S O, ALSUHYBANI M S, et al.Manufacturing of Carbon Fiber Reinforced Thermoplastics and Its Recovery of Carbon Fiber: A Review[J]. Polymer Testing, 2023, 122: 108029.
[7] 赵子岳. 碳纤维增强聚芳醚酮/聚醚醚酮热塑性复合材料二次成型工艺研究[D]. 上海: 东华大学, 2023: 1-3.
ZHAO Z Y.Overmolding Process of Carbon Fiber Reinforced Poly Aryl Ether Ketone/Poly Ether Ether Ketone Thermoplastic Composites[D]. Shanghai: Donghua University, 2023: 1-3.
[8] 石武平. 纤维增强热塑性复合构件热压-注塑工艺及力学性能研究[D]. 长沙: 中南大学, 2022: 2-6.
SHI W P.Investigation on the Hot Pressing-injection Process and Mechanical Properties of Fiber Reinforced Thermoplastic Composite Components[D]. Changsha: Central South University, 2022: 2-6.
[9] DENG T, HUANG Z G, CHEN L, et al.Injection Over-Molding Warpage Prediction of Continuous Fiber-Reinforced Thermoplastic Composites Considering Yarn Reorientation[J]. Thin-Walled Structures, 2022, 180: 109804.
[10] 郑津烁. 连续纤维增强热塑性复合材料嵌件包覆注塑成型研究[D]. 北京: 北京化工大学, 2025: 1-3.
ZHENG J S.Insert Overmolding of Continuous-Fiber- Reinforced Thermoplastic Composites[D]. Beijing: Beijing University of Chemical Technology, 2025: 1-3.
[11] COLLINS C, BATISTA N L, HUBERT P.Warpage Investigation of Carbon/PEEK Discontinuous Long Fibre Thin Panels[J]. Journal of Composite Materials, 2021, 55(24): 3529-3537.
[12] LANDRY B, HUBERT P.Experimental Study of Defect Formation during Processing of Randomly-Oriented Strand Carbon/PEEK Composites[J]. Composites Part A: Applied Science and Manufacturing, 2015, 77: 301-309.
[13] WAN Y, TAKAHASHI J.Molding Process Effects on the Internal Structures of High-Performance Discontinuous Carbon Fiber Reinforced Thermoplastics[J]. Journal of Composites Science, 2025, 9(6): 270.
[14] WAN Y, TAKAHASHI J.Tensile and Compressive Properties of Chopped Carbon Fiber Tapes Reinforced Thermoplastics with Different Fiber Lengths and Molding Pressures[J]. Composites Part A: Applied Science and Manufacturing, 2016, 87: 271-281.
[15] YAMASHITA S, HASHIMOTO K, SUGANUMA H, et al.Experimental Characterization of the Tensile Failure Mode of Ultra-Thin Chopped Carbon Fiber Tape-Reinforced Thermoplastics[J]. Journal of Reinforced Plastics and Composites, 2016, 35(18): 1342-1352.
[16] WAN Y, TAKAHASHI J.Tensile Properties and Aspect Ratio Simulation of Transversely Isotropic Discontinuous Carbon Fiber Reinforced Thermoplastics[J]. Composites Science and Technology, 2016, 137: 167-176.
[17] NAKASHIMA Y, YAMASHITA S, ZHANG X, et al.Analytical Modelling of the Behaviour and Scatter of the Flexural Modulus of Randomly Oriented Carbon Fibre Strand Thermoplastic Composites[J]. Composite Structures, 2017, 178: 217-224.
[18] WAN Y, TAKAHASHI J.Mechanical Modeling of CF/PA6 Sheet Molding Compounds with X-Ray Computed Tomography-Based Internal Geometry Considerations[J]. Composites Science and Technology, 2020, 192: 108104.
[19] TIE Q L, MING Q Z, HAN M Z. Processing Dependent Morphology, Interfacial Interaction and Shear Behavior of Short Carbon Fiber Reinforced PEEK, 2001, 32(12): 1727-1733.
[20] 孙佳伟. 碳纤维锻造复合材料模压成型及其拉伸和摩擦性能研究[D]. 广州: 华南理工大学, 2018: 20-28.
SUN J W.Molding and Properties Study on Tensile and Friction of Carbon Fiber Forged Composites[D]. Guangzhou: South China University of Technology, 2018: 20-28.
[21] LEGER E, LANDRY B, LAPLANTE G.High Flow Compression Molding for Recycling Discontinuous Long Fiber Thermoplastic Composites[J]. Journal of Composite Materials, 2020, 54(23): 3343-3350.
[22] KRAVCHENKO S G, VOLLE C, KRAVCHENKO O G.An Experimental Investigation on Low-Velocity Impact Response and Compression after Impact of a Stochastic, Discontinuous Prepreg Tape Composite[J]. Composites Part A: Applied Science and Manufacturing, 2021, 149: 106524.
[23] WAN Y, SUGANUMA H, TAKAHASHI J.Effects of Fabrication Processes and Tape Thickness on Tensile Properties of Chopped Carbon Fiber Tape Reinforced Thermoplastics[J]. Composites Communications, 2020, 22: 100434.
[24] SELEZNEVA M, LESSARD L.Characterization of Mechanical Properties of Randomly Oriented Strand Thermoplastic Composites[J]. Journal of Composite Materials, 2016, 50(20): 2833-2851.
[25] FERABOLI P, PEITSO E, DELEO F, et al.Characterization of Prepreg-Based Discontinuous Carbon Fiber/Epoxy Systems[J]. Journal of Reinforced Plastics and Composites, 2008, 28(10): 1191-1214.
[26] 李琦, 包祖国, 李杰, 等. 纤维波纹缺陷对拉挤成型复合材料刚度的影响[J]. 复合材料学报, 2025, 42(10): 6037-6048.
LI Q, BAO Z G, LI J, et al.Effects of Fiber Waviness Defects on Stiffness of Pultrusion Composites[J]. Acta Materiae Compositae Sinica, 2025, 42(10): 6037-6048.