目的 研究Cr-Ni-Co-Mo系超高强马氏体不锈钢动态再结晶行为,为热加工工艺优化提供指导。方法 以Cr-Ni-Co-Mo系超高强不锈钢为研究对象,利用热模拟试验机Gleeble开展了变形温度为1 050~1 150 ℃、应变速率为0.001~0.1 s-1的等温恒应变速率热压缩实验。基于流变应力曲线,建立了动态再结晶动力学的JMAK(Johnson-Mehl-Avrami-Kolmogorov)模型,对比了模型预测值与实验值,验证了模型的预测精度。将模型嵌入DEFORM-3D软件中,分析了Cr-Ni-Co-Mo系超高强不锈钢热加工过程中的变形特征。结果 在镦粗与拔长过程中,实验钢的温度场、应变场及组织场均发生显著的动态演化,表现出复杂的热-力-组织多场耦合效应。在镦粗阶段,实验钢内部有明显升温,最高温度可达1 170 ℃,应变集中于心部。在拔长阶段,等效应变进一步增大,表层区域应变增加,高于心部应变值,最高可达1.8,实验钢组织发生动态再结晶,奥氏体晶粒发生明显细化。结论 所建立的动态再结晶动力学JMAK模型具有较高的预测精度。耦合了再结晶动力学的锻造模型有助于进一步揭示Cr-Ni-Co-Mo系超高强马氏体不锈钢热加工过程的演变规律,为热加工过程工艺优化提供理论依据。
Abstract
The work aims to study the dynamic recrystallization behavior of Cr-Ni-Co-Mo ultra-high strength martensitic stainless steel to provide guidance for hot working process optimization. With Cr-Ni-Co-Mo ultra-high strength stainless steel as the research subject, isothermal constant strain rate hot compression experiments were conducted using a Gleeble thermal simulation tester under deformation temperatures of 1 050-1 150 ℃ and strain rates of 0.001-0.1 s-1. Through analysis of flow stress curves, a JMAK (Johnson-Mehl-Avrami-Kolmogorov) model for dynamic recrystallization kinetics was established. The predictive accuracy of the model was verified by comparing its calculated values with experimental data. Furthermore, the model was integrated into DEFORM-3D software to analyze deformation characteristics during the hot working process of Cr-Ni-Co-Mo ultra-high strength stainless steel. During the upsetting and stretching processes, the temperature field, strain field, and microstructure field of the experimental steel underwent significant dynamic evolution, demonstrating complex multi-field coupling effects involving thermal, mechanical and microstructural interactions. During upsetting, the internal temperature of the steel notably increased (peak 1 170 ℃) with strain concentration in the core region. In the stretching stage, equivalent strain further increased to 1.8 maximum, accompanied by dynamic recrystallization. In conclusion, the developed JMAK model for dynamic recrystallization kinetics exhibits high predictive accuracy, validated by experimental data. Coupling this model with forging simulations enables deeper insights into the hot-deformation mechanisms of Cr-Ni-Co-Mo martensitic ultra-high-strength stainless steel, providing a theoretical basis for optimizing thermal processing parameters.
关键词
超高强不锈钢 /
高温奥氏体 /
动态再结晶 /
热变形 /
数值模拟
Key words
ultra-high stainless steel /
high-temperature austenitic /
dynamic recrystallization /
hot deformation /
numerical simulation
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参考文献
[1] LIU Z B, LIANG J X, SU J, et al.Research and Application Progress in Ultra-High Strength Stainless Steel[J]. Acta Metallurgica Sinica, 2020, 56(4): 549-557.
[2] LI X Y, ZHANG Z H, CHENG X W, et al.The Investigation on Johnson-Cook Model and Dynamic Mechanical Behaviors of Ultra-High Strength Steel M54[J]. Materials Science and Engineering: A, 2022, 835: 142693.
[3] YANG Z, LIU Z B, LIANG J X, et al.Elucidating the Role of Secondary Cryogenic Treatment on Mechanical Properties of a Martensitic Ultra-High Strength Stainless Steel[J]. Materials Characterization, 2021, 178: 111277.
[4] SAKAI T, BELYAKOV A, KAIBYSHEV R, et al.Dynamic and Post-Dynamic Recrystallization under Hot, Cold and Severe Plastic Deformation Conditions[J]. Progress in Materials Science, 2014, 60: 130-207.
[5] ZHANG H K, XIAO H, FANG X W, et al.A Critical Assessment of Experimental Investigation of Dynamic Recrystallization of Metallic Materials[J]. Materials & Design, 2020, 193: 108873.
[6] MISHRA B, SINGH V, SARKAR R, et al.Dynamic Recovery and Recrystallization Mechanisms in Secondary B2 Phase and Austenite Matrix during Hot Deformation of Fe-Mn-Al-C-(Ni) Based Austenitic Low-Density Steels[J]. Materials Science and Engineering: A, 2022, 842: 143095.
[7] 潘品李, 钟约先, 马庆贤, 等. 核电主管道锻件锻造成形均匀性模拟研究[J]. 机械工程学报, 2013, 49(10): 97-102.
PAN P L, ZHONG Y X, MA Q X, et al.Simulation on Forming Uniformity of Nuclear Main Pipe Forging[J]. Journal of Mechanical Engineering, 2013, 49(10): 97-102.
[8] 刘东, 罗子健. 基于显微组织演化的本构关系的有限元变形-传热-组织演化耦合分析方法[J]. 塑性工程学报, 2006, 13(1): 62-66.
LIU D, LUO Z J.Method for Deformation-Heat Transfer-Microstructure Evolution Coupling Analysis via Constitutive Relationship Based on Microstructural Evolution[J]. Journal of Plasticity Engineering, 2006, 13(1): 62-66.
[9] LIN Y C, NONG F Q, CHEN X M, et al.Microstructural Evolution and Constitutive Models to Predict Hot Deformation Behaviors of a Nickel-Based Superalloy[J]. Vacuum, 2017, 137: 104-114.
[10] LI Y J, ZHANG Y, CHEN Z Y, et al.Hot Deformation Behavior and Dynamic Recrystallization of GH690 Nickel-Based Superalloy[J]. Journal of Alloys and Compounds, 2020, 847: 156507.
[11] QUAN G Z, ZHANG K K, AN C, et al.Analysis of Dynamic Recrystallization Behaviors in Resistance Heating Compressions of Heat-Resistant Alloy by Multi-Field and Multi-Scale Coupling Method[J]. Computational Materials Science, 2018, 149: 73-83.
[12] WU H, LIU M X, WANG Y, et al.Experimental Study and Numerical Simulation of Dynamic Recrystallization for a FGH96 Superalloy during Isothermal Compression[J]. Journal of Materials Research and Technology, 2020, 9(3): 5090-5104.
[13] 闫洞旭, 方实年, 蒲春雷, 等. 高强钢筋热压缩过程的本构分析及有限元模拟[J]. 中国冶金, 2021, 31(3): 50-58.
YAN D X, FANG S N, PU C L, et al.Constitutive Analysis and Finite Element Simulation of High-Strength Rebar during Hot Compression Process[J]. China Metallurgy, 2021, 31(3): 50-58.
[14] WANG L, CHEN C, WANG Z Y, et al.Effect of Hot Deformation Parameters on Dynamic Recrystallisation Mechanisms of Super Austenitic Stainless Steel[J]. Materials Science and Technology, 2022, 38(2): 78-89.
[15] LUO P, HU C D, WANG Q, et al.Microstructure Simulation and Experiment Investigation of Dynamic Recrystallization for Ultra High Strength Steel during Hot Forging[J]. Journal of Materials Research and Technology, 2023, 26: 4310-4328.
[16] 杜忠泽, 齐泽江, 党雪, 等. SCM435钢的热压缩流变行为及组织演变[J]. 金属热处理, 2024, 49(1): 76-83.
DU Z Z, QI Z J, DANG X, et al.Rheological Behavior and Microstructure Evolution of SCM435 Steel under Thermal Compression[J]. Heat Treatment of Metals, 2024, 49(1): 76-83.
[17] CHANG Y, MENG Z H, YING L, et al.Influence of Hot Press Forming Techniques on Properties of Vehicle High Strength Steels[J]. Journal of Iron and Steel Research, International, 2011, 18(5): 59-63.
[18] DONG H B, KANG Y L, YU H.A Discussion on Evolution of Micro-structures and Influence Factors During Continuous Rolling of Compact Strip Production[J]. Journal of Materials Science & Technology, 2009, 20: 274-278.
[19] 汪大年. 金属塑性成形原理[M]. 北京: 机械工业出版社, 1986.
WANG D N.Principle of Metal Plastic Forming[M]. Beijing: China Machine Press, 1986.
[20] 吕炎. 锻压成形理论与工艺[M]. 北京: 机械工业出版社, 1991: 128-130.
LYU Y.Theory and Technology of Forging Forming[M]. Beijing: China Machine Press, 1991: 128-130.
[21] FOLLANSBEE P S, KOCKS U F.A Constitutive Description of the Deformation of Copper Based on the Use of the Mechanical Threshold Stress as an Internal State Variable[J]. Acta Metallurgica, 1988, 36(1): 81-93.
[22] HOSFORD W F.Mechanical Behavior of Materials[M]. London: Cambridge University Press, 2009.
[23] 高兴健, 刘鑫, 罗健, 等. DP1180钢的热变形Arrhenius本构模型[J]. 精密成形工程, 2024, 16(11): 108-116.
GAO X J, LIU X, LUO J, et al.Arrhenius Constitutive Model for Hot Deformation of DP1180 Steel[J]. Journal of Netshape Forming Engineering, 2024, 16(11): 108-116.
[24] LAASRAOUI A, JONAS J J.Prediction of Steel Flow Stresses at High Temperatures and Strain Rates[J]. Metallurgical Transactions A, 1991, 22(7): 1545-1558.
[25] AVRAMI M.Kinetics of Phase Change. II Transformation-Time Relations for Random Distribution of Nuclei[J]. The Journal of Chemical Physics, 1940, 8(2): 212-224.
[26] SELLARS C M.Hot Working and Forming Processes[M]. London: The Metals Society, 1980: 3-15.
[27] JONAS J J, QUELENNEC X, JIANG L, et al.The Avrami Kinetics of Dynamic Recrystallization[J]. Acta Materialia, 2009, 57(9): 2748-2756.
[28] CAO R Z, WANG W, MA S B, et al.Arrhenius Constitutive Model and Dynamic Recrystallization Behavior of 18CrNiMo7-6 Steel[J]. Journal of Materials Research and Technology, 2023, 24: 6334-6347.
[29] WANG W, MA R, LI L P, et al.Constitutive Analysis and Dynamic Recrystallization Behavior of As-Cast 40CrNiMo Alloy Steel during Isothermal Compression[J]. Journal of Materials Research and Technology, 2020, 9(2): 1929-1940.
[30] CHAMANFAR A, VALBERG H S, TEMPLIN B, et al.Development and Validation of a Finite-Element Model for Isothermal Forging of a Nickel-Base Superalloy[J]. Materialia, 2019, 6: 100319.
[31] SLATER C, TAMANNA N, DAVIS C.Optimising Compression Testing for Strain Uniformity to Facilitate Microstructural Assessment during Recrystallisation[J]. Results in Materials, 2021, 11: 100218.
[32] 贾丹, 陈国胜, 王资兴, 等. GH4169合金铸锭开坯过程的热力耦合有限元模拟[J]. 钢铁研究学报, 2011, 23(S2): 150-153.
JIA D, CHEN G S, WANG Z X, et al.Thermal-Mechanical Coupling Finite Element Simulation of Opening Process of GH4169 Alloy Ingot[J]. Journal of Iron and Steel Research, 2011, 23(S2): 150-153.
[33] ZHANG Z J, DAI G Z, WU S N, et al.Simulation of 42CrMo Steel Billet Upsetting and Its Defects Analyses during Forming Process Based on the Software DEFORM-3D[J]. Materials Science and Engineering: A, 2009, 499(1/2): 49-52.
[34] BANASZEK G, BAJOR T, KAWAŁEK A, et al. Analysis of the Open Die Forging Process of the AZ91 Magnesium Alloy[J]. Materials, 2020, 13(17): 3873.
[35] CHOI S K, CHUN M S, VAN TYNE C J, et al. Optimization of Open Die Forging of round Shapes Using FEM Analysis[J]. Journal of Materials Processing Technology, 2006, 172(1): 88-95.
[36] OBIKO J O, MWEMA F M, BODUNRIN M O.Finite Element Simulation of X20CrMoV121 Steel Billet Forging Process Using the Deform 3D Software[J]. SN Applied Sciences, 2019, 1(9): 1044.
基金
钒钛资源综合利用产业技术创新战略联盟协同研发项目