不同热处理工艺对新型Ti421合金组织及性能的影响

桑卓越, 王帅, 尹万兵, 朱春明, 白张, 王鹏, 罗金山, 张永伟, 方略, 李晓燚, 周志明

精密成形工程 ›› 2025, Vol. 17 ›› Issue (9) : 70-78.

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精密成形工程 ›› 2025, Vol. 17 ›› Issue (9) : 70-78. DOI: 10.3969/j.issn.1674-6457.2025.09.006
轻合金成形

不同热处理工艺对新型Ti421合金组织及性能的影响

  • 桑卓越1,2, 王帅3, 尹万兵3, 朱春明3, 白张2, 王鹏2, 罗金山3, 张永伟3, 方略3, 李晓燚3, 周志明1,*
作者信息 +

Effect of Different Heat Treatments on the Microstructure and Mechanical Properties of a Novel Ti421 Alloy

  • SANG Zhuoyue1,2, WANG Shuai3, YIN Wanbing3, ZHU Chunming3, BAI Zhang2, WANG Peng2, LUO Jinshan3, ZHANG Yongwei3, FANG Lue3, LI Xiaoyi3, ZHOU Zhiming1,*
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摘要

目的 实现新型Ti421合金的良好强塑匹配效果。方法 研究水冷、空冷及炉冷等不同固溶冷却方式及不同时效温度热处理工艺对合金组织及性能的影响。结果 在相同的时效处理工艺条件下,固溶冷却速率的降低会导致在合金组织中等轴初生α相(αp)含量显著提高的同时尺寸略微增加。同时αp的存在也会抑制时效处理过程中次生α相(αs)的生长。结合静态拉伸测试结果发现,含量较多的αp对合金的塑性较有利。在经过900 ℃固溶炉冷后500 ℃时效处理的合金试样组织中,αp的体积分数达到了最大值72.8%,此时合金具有最好的塑性(14.2%)。此外,在固溶工艺固定的条件下,时效处理制度的改变基本不影响αp含量及尺寸的变化,但随着时效温度的升高,βt上αs含量增加且尺寸增大,导致合金强度呈现出先升高后降低的趋势。经过900 ℃固溶水冷+550 ℃时效处理后的合金实现了抗拉强度(UTS)为1 484 MPa、延伸率(EL)为11.2%的良好强塑匹配效果。

Abstract

The work aims to obtain the good strength-plastic matching effect of the novel Ti421 alloy. The microstructure and mechanical properties of a novel Ti421 alloy treated by different solution and aging processes were studied. Firstly, under the same aging process, a decrease in the cooling rate after solution treatment led to a significant increase in the content of equiaxed primary α phase (αp) of the alloy, accompanied by a slight increase in size of αp. At the same time, the presence of αp also inhibited the growth of the secondary α phase (αs) of the alloy during the aging process. Combined with the static tensile test results, it was found that more αp was beneficial to the plasticity of the alloy. After solution treatment at 900 ℃ and furnace cooling and aging treatment at 500 ℃, the content of αp of the sample reached the maximum value of 72.8%, indicating that the alloy had the best plasticity (14.2%). In addition, under the fixed conditions of solution treatment, changes in the aging treatment system did not cause the changes in the content and size of αp. However, with the increase of aging temperature, the content and size of αs on βt increased, which led to the trend that the alloy strength firstly increased and then decreased. The alloy achieves good strength-plastic matching with a tensile strength of 1 484 MPa and an elongation of 11.2% after solution treatment at 900 ℃ and water quenching followed with aging treatment at 550 ℃.

关键词

新型Ti421合金 / 微观组织 / 固溶时效处理 / 静态拉伸性能

Key words

novel Ti421 alloy / microstructure / solution and aging treatment / static tensile properties

引用本文

导出引用
桑卓越, 王帅, 尹万兵, 朱春明, 白张, 王鹏, 罗金山, 张永伟, 方略, 李晓燚, 周志明. 不同热处理工艺对新型Ti421合金组织及性能的影响[J]. 精密成形工程. 2025, 17(9): 70-78 https://doi.org/10.3969/j.issn.1674-6457.2025.09.006
SANG Zhuoyue, WANG Shuai, YIN Wanbing, ZHU Chunming, BAI Zhang, WANG Peng, LUO Jinshan, ZHANG Yongwei, FANG Lue, LI Xiaoyi, ZHOU Zhiming. Effect of Different Heat Treatments on the Microstructure and Mechanical Properties of a Novel Ti421 Alloy[J]. Journal of Netshape Forming Engineering. 2025, 17(9): 70-78 https://doi.org/10.3969/j.issn.1674-6457.2025.09.006
中图分类号: TG166.5   

参考文献

[1] BANERJEE D, WILLIAMS J C.Perspectives on Titanium Science and Technology[J]. Acta Materialia, 2013, 61(3): 844-879.
[2] CUI C X, HU B M, ZHAO L C, et al.Titanium Alloy Production Technology, Market Prospects and Industry Development[J]. Materials & Design, 2011, 32(3): 1684-1691.
[3] LI X Y, YANG J Y. Production, Characterisation,Application of Titanium Gypsum: A Review[J]. Process Safety and Environmental Protection, 2024, 181: 64-74.
[4] WEI G J, TAN M Y, ATTARILAR S, et al.An Overview of Surface Modification, a Way Toward Fabrication of Nascent Biomedical Ti-6Al-4V Alloys[J]. Journal of Materials Research and Technology, 2023, 24: 5896-5921.
[5] 周宗熠, 相志磊, 马小昭, 等. 高强β钛合金的发展现状与强化方法[J]. 北京工业大学学报, 2024, 50(5): 620-631.
ZHOU Z Y, XIANG Z L, MA X Z, et al.Development Status and Strengthening Methods of High-Strength β-Titanium Alloys[J]. Journal of Beijing University of Technology, 2024, 50(5): 620-631.
[6] NAYDENKIN E V, MISHIN I P, OBORIN V A, et al.Effect of Combined Rolling with Subsequent Aging on the Structure, Mechanical and Fatigue Properties of β Titanium Alloy[J]. Materials Letters, 2021, 300: 130132.
[7] 吴欢, 赵永庆, 葛鹏, 等. β稳定元素对钛合金α相强化行为的影响[J]. 稀有金属材料与工程, 2012, 41(5): 805-810.
WU H, ZHAO Y Q, GE P, et al.Effect of β Stabilizing Elements on the Strengthening Behavior of Titanium α Phase[J]. Rare Metal Materials and Engineering, 2012, 41(5): 805-810.
[8] 张永强, 郭鸿镇, 孙红兰, 等. 热处理对TC18合金显微组织和力学性能的影响[J]. 热加工工艺, 2012, 41(6): 147-149.
ZHANG Y Q, GUO H Z, SUN H L, et al.Effect of Heat Treatment on Microstructure and Mechanical Properties of TC18 Alloy[J]. Hot Working Technology, 2012, 41(6): 147-149.
[9] 张关梅, 黄海广, 张浩泽, 等. 轧制温度对TA31钛合金热轧板材组织与性能的影响[J]. 塑性工程学报, 2022, 29(11): 224-232.
ZHANG G M, HUANG H G, ZHANG H Z, et al.Effect of Rolling Temperature on Microstructure and Properties of TA31 Titanium Alloy Hot Rolled Plate[J]. Journal of Plasticity Engineering, 2022, 29(11): 224-232.
[10] 张珍宣, 雷旻, 朱红, 等. 固溶温度和冷却速率对TC21钛合金组织和力学性能的影响[J]. 热加工工艺, 2016, 45(8): 217-220.
ZHANG Z X, LEI M, ZHU H, et al.Effect of Solution Temperature and Cooling Rate on Microstructure and Mechanical Properties of TC21 Titanium Alloy[J]. Hot Working Technology, 2016, 45(8): 217-220.
[11] LI D R, WANG K, YAN Z B, et al.Evolution of Microstructure and Tensile Properties during the Three-Stage Heat Treatment of TA19 Titanium Alloy[J]. Materials Science and Engineering: A, 2018, 716: 157-164.
[12] XIONG F Y, HUANG C Y, KAFKA O L, et al.Grain Growth Prediction in Selective Electron Beam Melting of Ti-6Al-4V with a Cellular Automaton Method[J]. Materials & Design, 2021, 199: 109410.
[13] YANG X, XI Z P, LIU Y, et al.Microstructure and Fracture Toughness of a TiAl-Nb Composite Consolidated by Spark Plasma Sintering[J]. Transactions of Nonferrous Metals Society of China, 2012, 22(11): 2628-2632.
[14] SEMIATIN S L, SEETHARAMAN V, WEISS I.Flow Behavior and Globularization Kinetics during Hot Working of Ti-6Al-4V with a Colony Alpha Microstructure[J]. Materials Science and Engineering: A, 1999, 263(2): 257-271.
[15] DEHGHAN-MANSHADI A, DIPPENAAR R J.Development of α-Phase Morphologies during Low Temperature Isothermal Heat Treatment of a Ti-5Al-5Mo-5V-3Cr Alloy[J]. Materials Science and Engineering: A, 2011, 528(3): 1833-1839.
[16] WANG Y L, HAO M Y, LI D, et al.Enhanced Mechanical Properties of Ti-5Al-5Mo-5V-3Cr-1Zr by Bimodal Lamellar Precipitate Microstructures via Two-Step Aging[J]. Materials Science and Engineering: A, 2022, 829: 142117.
[17] 盖晋阳, 程军, 于振涛, 等. β型钛合金细化α析出相的方法及研究现状[J]. 热加工工艺, 2020, 49(14): 1-5.
GAI J Y, CHENG J, YU Z T, et al.Methods and Research Status of Refinement of α Precipitates in β-Type Titanium Alloy[J]. Hot Working Technology, 2020, 49(14): 1-5.
[18] YIN M, LUO H J, DENG H, et al.Thermomechanical Processing of Near-β Ti-5Al-5Mo-5V-1Cr-1Fe Alloys: Effect of Deformation Reduction on Microstructures and Mechanical Properties[J]. Materials Science and Engineering: A, 2022, 853: 143786.
[19] SRINIVASU G, NATRAJ Y, BHATTACHARJEE A, et al.Tensile and Fracture Toughness of High Strength β Titanium Alloy, Ti-10V-2Fe-3Al, as a Function of Rolling and Solution Treatment Temperatures[J]. Materials & Design, 2013, 47: 323-330.
[20] 李艳英, 李旻萱, 欧阳斌, 等. Ti-55531钛合金室温强-塑-韧匹配化热处理工艺研究[J]. 精密成形工程, 2023, 15(12): 68-78.
LI Y Y, LI M X, OUYANG B, et al.Investigation into the Heat Treatment Technology to Enhance the Compatibility among the Tensile Strength, Ductility, and Fracture Toughness of Ti-55531 Alloy[J]. Journal of Netshape Forming Engineering, 2023, 15(12): 68-78.
[21] ZHU W G, LEI J, ZHANG Z X, et al.Microstructural Dependence of Strength and Ductility in a Novel High Strength β Titanium Alloy with Bi-Modal Structure[J]. Materials Science and Engineering: A, 2019, 762: 138086.
[22] 王俭, 冯秋元, 雷挺, 等. 退火温度对低成本TC4钛合金板材组织和性能的影响[J]. 金属热处理, 2022, 47(11): 82-86.
WANG J, FENG Q Y, LEI T, et al.Effect of Annealing Temperature on Microstructure and Properties of Low Cost TC4 Titanium Alloy Plate[J]. Heat Treatment of Metals, 2022, 47(11): 82-86.
[23] 王幸运, 黄文彬, 乔恩利, 等. 双重时效处理对β21S钛合金棒材组织性能的影响[J]. 金属热处理, 2022, 47(10): 198-202.
WANG X Y, HUANG W B, QIAO E L, et al.Effect of Double Aging Treatment on Microstructure and Properties of β21S Titanium Alloy Bar[J]. Heat Treatment of Metals, 2022, 47(10): 198-202.
[24] SADEGHPOUR S, ABBASI S M, MORAKABATI M, et al.Correlation between Alpha Phase Morphology and Tensile Properties of a New Beta Titanium Alloy[J]. Materials & Design, 2017, 121: 24-35.
[25] HERASYMCHUK O M.Microstructurally-Dependent Model for Predicting the Kinetics of Physically Small and Long Fatigue Crack Growth[J]. International Journal of Fatigue, 2015, 81: 148-161.

基金

重庆市教委重大科研项目(KJZD-M202401104); 重庆市科技计划基金(2023-JCJQ-JJ-2001,2024-JCJQ-JJ-2026); 绍兴英才项目(2022SXRC); 重庆理工大学科研项目(2024TBA025)

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